Abstract
Epoxidation of Nahor oil was performed by H2O2 in the presence of acid catalyst at 50 °C. It was possible to obtain around 70% epoxide yield within 8 hrs of reaction. Amberlite IR 120H showed better epoxide yield compared to H2SO4 and Dowex 50 WX8. The performance of carboxylic acids was found to be in the order of formic acid>acetic acid>propanoic acid. The curing of epoxidized nahor oil involved using ethylenediamine (EDA) and diethylenetriamine (DETA). The adhesive property of the cured resins was tested and compared with commercially available glue. The force required to detach the cardboard joint was about 36.3 N for DETA-cured resin.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
N. Kim, Y. Li and X. S. Sun, Ind. Crops. Prod., 64, 1 (2015).
L. H. Gan, K. S. Ooi, L. M. Gan and S. H. Goh, J. Am. Oil Chem. Soc., 72, 439 (1995).
V. B. Borugadda and V. V. Goud, Energy Procedia, 54, 75 (2014).
M.M. Ewumbua, M. H. Darrin and P.W. Dennis, Ind. Crops. Prod., 67, 364 (2015).
K. G. Padmasiri, O.B. Michael and K. J. Laleen, National Sci. Found. Sri Lanka., 37, 229 (2009).
F. E. Okieimen, O. I. Bakare and C.O. Okieimen, Ind. Crops. Prod., 15, 139 (2002).
L. A. Rios, P. Weckes, H. Schuster and W. F. Hoelderich, J. Catal., 232, 19 (2005).
B. Rangarajan, A. Havey, E.A. Grulke and P.D. Culnan, J. Am. Oil Chem. Soc., 72, 1161 (1995).
M. Janković and S. S. Fišer, J. Am. Oil Chem. Soc., 82, 301 (2005).
U. Biermann, W. Friedt, S. Lang, W. Luhs, G. Machmuller, J.O. Metzger, M.R. Klaas, H. J. Schafer and M. P. Schneider, Angew. Chem. Int. Ed., 39, 2206 (2000).
M.R. Klaas and S. Warwel, Ind. Crops. Prod., 9, 125 (1999).
S. Dinda, V. V. Goud, A. V. Patwardhan and N. C. Pradhan, Asia-Pac. J. Chem. Eng., 6, 870 (2011).
S. Dinda, A.V. Patwardhan, V.V. Goud and N. C. Pradhan, Bioresour. Technol., 99, 3737 (2008).
V.V. Goud, S. Dinda, A.V. Patwardhan and N. C. Pradhan, Asia-Pac. J. Chem. Eng., 5, 346 (2010).
V.V. Goud, A.V. Patwardhan, S. Dinda and N. C. Pradhan, Chem. Eng. Sci., 62, 4065 (2007).
F.G. Garcia, M. E. Leyva, A. A. A. de Queiroz and A. Z. Simoes, Int. J. Adhes. Adhes., 31, 177 (2011).
Y. Liu, G. Yang, H. M. Xiao, Q. P. Feng and S.T. Fu, Int. J. Adhes. Adhes., 41, 113 (2013).
K.B. Katnam, A. J. Comer, W.F. Stanley, M. Buggy and T.M. Young, Int. J. Adhes. Adhes., 37, 3 (2012).
D.K. Salunkhe, J. K. Chavan, R. N. Adsule and S. S. Kadam, World Oilseeds: Chemistry, Technology and Utilization, first Ed., Van Nostrand Reinhold, New York (1992).
S. Siggia and J. G. Hanna, Quantitative Organic Analysis via Functional Groups, 4th Ed., Wiley, New York (1979).
C. Pequot, Standard Methods for the Analysis of Oils, Fats and Derivatives, Part-1, fifth Ed., Pergamon Press, Germany (1979).
C.A. May, Epoxy Resins: Chemistry and Technology, Second Ed., Marcel Dekker, New York (1987).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Dinda, S., Veeram, N.S.R. & Adusumalli, R.B. Production of bio-epoxide and bio-adhesive from non-edible oil. Korean J. Chem. Eng. 33, 2915–2922 (2016). https://doi.org/10.1007/s11814-016-0136-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-016-0136-0