Abstract
This paper describes a dimethoate imprinted polymeric potentiometric sensor for the determination of dimethoate that was designed by dispersing the dimethoate-imprinted polymer in dibutyl phthalate plasticizer and then embedded in polyvinyl chloride matrix. The method is based on molecularly imprinted polymer (MIP), which can be synthesized by using dimethoate as a template molecule, chitosan-Cd(II), and 3-mercaptopropyl-trimethoxysilane as a functional monomer and TEOS, and ephychlorohydrin as a cross-linking agent. We have studied a method for the selective binding behavior of dimethoate compounds on the surface of imprinted polymers which is prepared using ligand-exchange (LE) (chitosan-Cd(II)) monomer. The MIP-LE-1 and MIP-LE-2 based membranes have shown a detection limit of 4.3×10−6 mmolL−1 and 3.5.10−5 mmolL−1, respectively. The sensor has exhibited a response time of 35min for MIP-LE-1 and 120min for MIP-LE-2. They are stable for more than three months.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
Z. L. Fan, G. L. Yang and H.Y. Liu, Chin. J. Chromatogr., 21, 199 (2003).
P.T. Vallano and V.T. Remcho, J. Chromatogr. A, 887, 125 (2000).
L. Qin, X.W. He, W. Zhang, W.Y. Li and Y.K. Zhang, J. Chromatogr. A, 1216, 807 (2009).
N. Lavignac, C. J. Allender and K.R. Brain, Anal. Chem. Acta, 510, 139 (2004).
J. S. Metcalf and G. A. Chem. Res. Toxicol., 16, 103 (2003).
D. Jégourel, R. Delépée, F. Breton, A. Rolland, R. Vidal and L. A. Agrofoglio, Bioorgan. Med. Chem., 16, 8932 (2008).
J. F. Yin, G. L. Yang and Y. Chen, J. Chromatogr. A, 1090, 68 (2005).
Y. Tan, H. Peng, C. Liang and S. Yao, Sens. Actuators B: Chem., 73, 179 (2001).
Y. C. Chen, J. J. Brazier, M.D. Yan, P. R. Bargo and S.A. Prahl, Sens. Actuators B: Chem., 102, 107 (2004).
R. Thoelen, R. Vansweevelt, J. Duchateau, F. Horemans, J. D’Haen, L. Lutsen, D. Vanderzande, M. Ameloot, M. vandeVen, T. J. Cleij and P. Wagner, Biosens. Bioelectron., 23, 913 (2008).
E. Mazzotta, R. A. Picca, C. Malitesta, S. A. Piletsky and E. V. Piletska, Biosens. Bioelectron., 23, 1152 (2008).
S. Dai, M.C. Burleigh, Y.H. Ju, H. J. Gao, J.S. Lin, S. J. Pennycook, C. E. Barnes and Z. L. Xue, J. Am. Chem. Soc., 122, 992 (2000).
Y. K. Lu and X. P. Yan, Anal. Chem., 76, 453 (2004).
E. L. Holthoff and F.V. Bright, Anal. Chim. Acta, 594, 147 (2007).
E. L. Shughart, K. Ahsan, M.R. Detty and F.V. Bright, Anal. Chem., 78, 3165 (2006).
E.V. Piletskaya, M. Romero-Guerra, I. Chianella, K. Karim, A. P. F. Turner and S. A. Piletsky, Anal. Chim. Acta, 542, 47 (2005).
S. A. Piletsky and A. P. F. Turner, Electroanalysis, 14(5), 317 (2002).
O.Y. F. Henry, D.C. Cullen and S.A. Piletsky, Anal. Bioanal. Chem., 382, 947 (2005).
K. Prasad, K. P. Prathish, J. Mary Gladis, G. R. K. Naidu and T. Prasada Rao, Sens. Actuator B Chem., 123, 65 (2007).
V. Vishnuvardhan, K. P. Prathish, G.R. K. Naidu and T. Rao, Electrochim. Acta, 52(24), 6922 (2007).
S. Sadeghi, F. Fathi and J. Abbasifar, Sens. Actuators B: Chem., 122, 158 (2007).
K.P. Prathish, K. Prasad, T. Prasada Rao and M.V.S. Suryanarayana, Acid Talanta, 71, 1976 (2007).
G. D’Agostino, G. Alberti, R. Biesuz and M. Pesavento, Biosens. Bioelectron, 22, 145 (2006).
Y. Zhou, B. Yu and K. Levon, Acid. Biosens. Bioelectron., 20, 1851 (2005).
Z. Zhou, B. Yu and K. Levon, Chem. Mater., 15, 2774 (2003).
M. Lahav, A. B. Kharitonov, O. Katz, T. Kunitake and I. Willner, Anal. Chem., 73, 720 (2001).
S. P. Pogorelova, T. Bourenko, A.B. Kharitonov and I. Willner, The Analyst, 127, 1484 (2002).
M. Javanbakht, S. Eynollahi, M. Abdouss, M. R. Ganjali, C. P. Norouzi and L. Safaraliee, Electroanalysis, 20, 2023 (2008).
M. Erdem, R. Say, A. Ersöz, A. Denizli and H. Türk, Appl. Clay Sci., 47, 223 (2010).
M. Odabasi, R. Say and A. Denizli, Mater. Sci. Eng. C, 27, 90 (2007).
Y. Umezawa, K. Umezawa and H. Sato, Pure Appl. Chem., 67, 507 (1995).
T. Imato and N. Ishibashi, Biosens. Bioelectron., 10, 435 (1995).
E. Khaleda, H.N.A. Hassana, Gehad G. Mohamed, F.A. Ragabc and Aly Eldin A., Talanta, 83, 357 (2010).
P. Mulchandani, A. Mulchandani, I. Kaneva and W. Chen, Biosens. Bioelectron., 14, 77 (1999).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Bektaşoğlu, E., Özkütük, E.B., Ersöz, A. et al. Double-imprinted potentiometric sensors based on ligand exchange for the determination of dimethoate. Korean J. Chem. Eng. 32, 1613–1617 (2015). https://doi.org/10.1007/s11814-014-0386-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-014-0386-7