Abstract
The effect of 1-(benzo[d]thiazol-2-yl)-3-chloro-4-(3,5-dichlorophenyl)-4-methylazetidin-2-one (BDMA) and 3-(benzo[d]thiazol-2-yl)-2-(3,5-dichlorophenyl)-2,5-dimethylthiazolidin-4-one (BDMT) on the corrosion of oil well tubular steel (N80 steel) in 15% hydrochloric acid solution was investigated by means of potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The surface morphology of the uninhibited and inhibited samples was studied with atomic force microscopy (AFM). The corrosion inhibition efficiency of both inhibitors increased with increasing inhibitors concentration. The adsorption of both inhibitor molecules on surface of N80 steel obeys Langmuir adsorption isotherm. Potentiodynamic polarization measurements indicated that both the studied inhibitors act as mixed type inhibitor. Quantum chemical calculations were carried out using density functional theory (DFT) to correlate the experimental results with the theoretical results.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
M. Yadav, D. Behera and U. Sharma, Corros. Eng. Sci. Technol., 48, 19 (2013).
S. Vishwanatham and P.K. Sinha, Anti-Corros. Methods Mater., 56, 139 (2009).
F. Bentiss, B. Mernari, M. Traisnel, H. Vezin and M. Lagrenée, Corros. Sci., 53, 487 (2011).
O. Benali, L. Larabi, M. Traisnel, L. Gengembra and Y. Harek, Appl. Surf. Sci., 253, 6130 (2007).
F. Bentiss, M. Lebrini and M. Lagrenee, Corros. Sci., 47, 2915 (2005).
J. Cruz, R. Martinez, J. Genesca and E. Garcia-Ochoa, Electroanal. Chem., 566, 111 (2004).
K. F. Khaled, Electrochim. Acta, 48, 2493 (2003).
K. Mistry and K. R. Desai, Indian J. Chem., 45B, 1762 (2006).
C. Lee, W. Yang and R.G. Parr, Phys. Rev. B, 37, 785 (1988).
X. Wang, H. Yang, F. Wang, X. Wang, H. Yang and F. Wang, Corros. Sci., 53, 113 (2011).
W. Li, Q. He, S. Zhang, B. Pei and B. Hou, J. Appl. Electrochem., 38, 289 (2008).
S. Ramesh, S. Rajeswari, Electrochim. Acta, 49, 811 (2004).
H. Ashassi-Sorkhabi, B. Shaabani and D. Seifzadeh, App. Surf. Sci., 239, 154 (2005).
S. M. Behpour, N. Ghoreishi, N. Mohammadi and M. Soltani, Corros. Sci., 52, 4046 (2010).
R. Solmaz, G. Kardas, M. Çulha, B. Yazici and M. Erbil, Electrochim. Acta, 53, 5941 (2008).
M. Özcan, I. Dehri and M. Erbil, Appl. Surf. Sci., 236, 155 (2004).
M. Lebrini, F. Robert, A. Lecante and C. Roos, Corros. Sci., 53, 687 (2011).
I. Dehri and M. Ozcan, Mater. Chem. Phys., 98, 316 (2006).
S. Ghareba and S. Omanovic, Electrochim. Acta, 56, 3890 (2011).
E. Machnikova, K. H. Whitmire and N. Hackerman, Electrochim. Acta, 53, 6024 (2008).
R. Solmaz Corros. Sci., 81, 75 (2014).
R. Solmaz Corros. Sci., 79, 169 (2014).
S. Xia, M. Qiu, L. Yu, F. Liu and H. Zhao, Corros. Sci., 50, 2021 (2008).
R. G. Pearson, Inorg. Chem., 27, 734 (1988).
I. Lukovits, E. Klaman and F. Zucchi, Corrosion, 57, 3 (2001).
Y.M. Tang, W.Z. Yang, X. S. Yin, Y. Liu, R. Wan and J.T. Wang, Mater. Chem. Phys., 116, 479 (2009).
M. K. Awad, M.R. Mustafa and M. M. Abo-Elnga, J. Mol. Model., 959, 66 (2010).
R. Hasanov, M. Sadikoglu and S. Bilgic, Appl. Surf. Sci., 253, 3913 (2007).
M.A. Amin, K. F. Khaled and S. A. Fadl-Allah, Corros. Sci., 55, 140 (2010).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Yadav, M., Sharma, D. & Kumar, S. Thiazole derivatives as efficient corrosion inhibitor for oil-well tubular steel in hydrochloric acid solution. Korean J. Chem. Eng. 32, 993–1000 (2015). https://doi.org/10.1007/s11814-014-0275-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-014-0275-0