Abstract
The carbon dioxide dry reforming of methane (CDR) reaction could be thermodynamically favored in the range of 800 to 1,000 °C. However, the catalyst in this reaction should be avoided at the calcination temperature over 800 °C since strong metal support interaction (SMSI) in this temperature range can decrease activity due to loss of active sites. Therefore, we focused on optimizing the temperature of pretreatment and a comparison of surface characterization results for CDR. Results related to metal sintering over support, re-dispersion by changing of particle size of metal-support, and strong metal support interaction were observed and confirmed in this work. In our conclusion, optimum calcination temperature for a preparation of catalyst was proposed that 400 °C showed a higher and more stable catalytic activity without changing of support characteristics.
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Song, SH., Son, JH., Budiman, A.W. et al. The influence of calcination temperature on catalytic activities in a Co based catalyst for CO2 dry reforming. Korean J. Chem. Eng. 31, 224–229 (2014). https://doi.org/10.1007/s11814-013-0211-8
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DOI: https://doi.org/10.1007/s11814-013-0211-8