Abstract
The catalytic applicability of ionic liquids immobilized on various support materials such as silica, polystyrene and biopolymers in the cycloaddition of carbon dioxide with epoxides is reviewed in this work. Comparisons of the catalytic efficiency of these various catalysts have been done from the aspect of turnover number and reusability. The studies revealed that ionic liquids or support materials possessing hydrogen bonding capable groups exhibited enhanced catalytic activity towards cyclic carbonate synthesis. Moreover, the increased quest towards environmentally benign materials has renewed the search for biocompatible materials as support for ionic liquids.
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Dae-Won Park is a professor in the School of Chemical and Biomolecular Engineering, Pusan National University, Korea. He obtained his Ph.D. in Chemical Reaction Engineering from University of Aix-Marseille III, France in 1984. He worked for two years at KRICT before joining Pusan National University in 1987. He was a visiting professor at the University of British Columbia and Tianjin University. He has over 250 scientific publications. Current research interests cover green catalysis, CO2 conversion and catalytic application of ionic liquids.
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Kim, DW., Roshan, R., Tharun, J. et al. Catalytic applications of immobilized ionic liquids for synthesis of cyclic carbonates from carbon dioxide and epoxides. Korean J. Chem. Eng. 30, 1973–1984 (2013). https://doi.org/10.1007/s11814-013-0193-6
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DOI: https://doi.org/10.1007/s11814-013-0193-6