Abstract
A series of cobalt and manganese catalysts supported on SBA-15 with different loading of Mn+2 and Co+2 were synthesized. These samples were characterized by SEM and XRD techniques. The catalytic activity of these samples was evaluated in the oxidation of ethylbenzene (EB) to produce acetophenone (AP) and benzoic acid (BA) in the liquid phase using tert-butylhydroperoxide (TBHP) as an oxidant. The effects of Co-Mn loading, TBHP: EB molar ratio and temperature on acetophenone and benzoic acid yields were studied by Box-Behnken experimental design to optimize the production of acetophenone and benzoic acid in liquid system.
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C. Turner, J. Brennan, P. Johnson and K. Gubbins, J. Chem. Phys. B, 116, 2138 (2002).
D. Zhao, J. Feng, Q. Huo, N. McIntosh, G. Fredrickson, B. Chmeika and G. Stucky, Science, 279, 548 (1998).
S. S. Reddy, D.R. Burri, V. S. Kumar, A. H. Padmasri, S. Narayanan and K. S. Rama Rao, Catal. Commun., 8, 261 (2007).
D. R. Burri, I. R. Shaikh, K.M. Choi and S. E. Park, Catal. Commun., 8, 731 (2007).
R. Bechara, D. Balloy and D. Vanhove, Appl. Catal. A: Gen., 207, 343 (2001).
D. Song and J. Li, J. Mol. Catal. A: Chem., 247, 206 (2006).
S. B. Shrikant, S. Shylesh, K.R. Kamble and A. P. Singh, J. Mol. Catal. A: Chem., 255, 123 (2006).
L. Jia, Litao Jia, D. Li, B. Hou, J. Wang and Y. Sun, J. Solid State Chem., 184, 488 (2011).
E.V. Steen, G. S. Swell, R.A. Makhothe, C. Micklethwaite, H. Manstein, M. D. Lange and C. T. O’Connor, J. Catal., 162, 220 (1996).
Y. Khodakov, V. L. Zholobenko, R. Bechara and D. Durand, Micropor. Mesopor. Mater., 79, 29 (2005).
Y. Khodakov, R. Bechara and A. Griboval-Constant, Appl. Catal. A: Gen., 254, 273 (2003).
S.W. Ho, M. Houalla and D.M. Hercules, J. Phys. Chem., 94, 6396 (1990).
J. Fei, Y. Cui, X. H. Yan, W. Qi, Y. Yang and J. B. Li, Adv. Mater., 20, 452 (2008).
W. Xiao, J. S. Chen, Q. Lu and X.W. Lou, J. Phys. Chem. C, 114, 12048 (2010).
J. J. Spivey, Ind. Eng. Chem. Res., 26, 2165 (1987).
R. H. Myer and D. C. Montgomery, Response surface methodology, 2nd Ed., Wiley, New York, 343 (2002).
S. Ray, Ind. Tex. J., 117, 24 (2006).
G.E. P. Box and N. R. Draper, Empirical model building and response surfaces, John Wiley & Sons Inc., New York, 477 (1987).
K. Yetilmezsoy, S. Demirel and R. J. Vanderbei, J. Hazard. Mater., 171, 551 (2009).
D. Bas and I. H. Boyac, J. Food Eng., 78, 836 (2007).
JMP, The statistical discovery software, user’s guide, SAS, USA (2009).
G. Du, Y. Yang, W. Qiu, S. Lim, L. Pfefferle and G. L. Haller, Appl. Catal. A: Gen., 313, 1 (2006).
P. Tripathi, V. Chandra Srivastava and A. Kumar, Desalination, 249, 1273 (2009).
S.Y. Lu, J. Q. Qian, G.W. Zhang, D.Y. Wei, G. F. Wu, B. P. Yi, B. Pan and K. Y. Zhang, J. Biochem. Technol., 1, 79 (2009).
Q. Tang, Y. Chen, C. Jasmine Zhou, T. Chen and Y. Yang, Catal. Lett., 128, 210 (2009).
I. Istadi and N. A. Saidina Amin, Fuel Process Technol., 87, 449 (2006).
N. Jose, S. Sengupta and J. K. Basu, Fuel, 90, 626 (2011).
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Mahdavi, V., Monajemi, A. Statistical optimization for oxidation of ethyl benzene over Co-Mn/SBA-15 catalyst by Box-Behnken design. Korean J. Chem. Eng. 30, 2178–2185 (2013). https://doi.org/10.1007/s11814-013-0182-9
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DOI: https://doi.org/10.1007/s11814-013-0182-9