Abstract
Well-dispersed palladium nanoparticles (Pd NPs) were prepared under the condition that trisodium citrate was the reduction agent and polyvinylpyrrolidone (PVP) was the stabilizing agent via sol-gel process. By making good use of the advanced electrospinning technology we obtained Pd NPs/PVP composite nanofibers films. Optical properties were examined by UV-visible absorbance spectra (UV-vis) and Fourier transform infrared spectroscopy (FTIR). The morphology and distribution of Pd NPs in/on PVP matrix were characterized by scanning electron microscope (SEM) and transmission electron microscope (TEM). The results showed that Pd NPs presented as spherical spots and distributed in/on PVP nanofibers uniformly; their diameter was 4–10 nm and decreased with the increase of PVP. The as-prepared Pd NPs/PVP hybrid mats possess catalytic activity, stability and reusability, as verified by performance in Heck reaction.
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Guo, L., Bai, J., Liang, H. et al. A facile approach to preparing palladium nanoparticles-embedded polyvinylpyrrolidone (PVP) heterogeneous hybrid nanofibers mats by electrospinning. Korean J. Chem. Eng. 30, 2142–2150 (2013). https://doi.org/10.1007/s11814-013-0173-x
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DOI: https://doi.org/10.1007/s11814-013-0173-x