Abstract
Experimentally measured data of excess molar volumes and enthalpies at 308.15 K for binary mixtures of formamide with 1-butanol or 2-methyl-1-propanol were fitted to the Redlich-Kister polynomial equation. Thermodynamics of molecular interaction in these mixtures was discussed using Prigogine-Flory-Patterson theory, Treszczanowicz-Benson association model and Graph theoretical approach. Extent of inter-molecular H-bonding in formamide and butanol in their binary mixtures was also reflected in their molar enthalpy of association of H-bonding Δh 0 H and association constant K H calculated from Treszczanowicz-Benson association model. All the three theories predict the excess property data reasonably well.
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Rani, M., Maken, S. Thermodynamics of molecular interactions in binary mixtures containing associated liquids. Korean J. Chem. Eng. 30, 1636–1643 (2013). https://doi.org/10.1007/s11814-013-0076-x
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DOI: https://doi.org/10.1007/s11814-013-0076-x