Abstract
The novelty of this work is the selective extraction of bismuth ions from nitrate medium by emulsion liquid membrane. Di(2-ethylhexyl)phosphoric acid was used as extractant of bismuth ions from nitrate medium by emulsion liquid membrane, and Triton X-100 was used as the biodegradable surfactant in n-pantanol n-pentanol bulk membrane. The extraction of bismuth ions was evaluated by the yield of extraction. The experimental parameters were evaluated and were optimized. They included the ratio of di(2-ethylhexyl)phosphoric acid concentration to the concentration of /Triton X-100 concentration (1.0: 0.5% w/w), nature of diluents (n-pentanol), nature and concentration of the stripping solution (sulfuric acid, 0.5M), stirring speed (1,800 rpm) and equilibrium time of extraction (20min), initial feed solution of bismuth (350 ppm) and the volume ratio of the internal stripping phase to the membrane phase (14 times). The experimental parameters of kinetic extraction revealed that the bismuth ions were extracted at 100% 97%.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
H. Z. Chen, M. C. Kao, S. L. Young, C. C. Yu, C. H. Lin, C.M. Lee and C. R. Ou, Thin Solid Films, 517, 4818 (2009).
F. Shemirani, M. Baghdadi, M. Ramezani and M. R. Jamali, Anal. Chim. Acta, 534, 163 (2005).
P. Thirupathi and S. S. Kim, Tetrahedron, 65, 5168 (2009).
J.G. Yang, J.Y. Yang, M. T. Tang, C. B. Tang and W. Liu, Hydrometallurgy, 96, 342 (2009).
K. Campos, R. Domingo, T. Vincent, M. Ruiz, A.M. Sastre and E. Guibal, Water Res., 42, 4019 (2008).
F. Habashi, Enc. Mater. Sci. Technol., 12, 332 (2008).
M. Chabani, A. Amrane and A. Bensmaili, Desalination, 206, 560 (2007).
M. Gautam and B. K. Purl, Mikrochim. Acta, 1, 515 (1979).
S. Kocaoba and G. Akcin, Desalination, 180, 151 (2005).
B. Mokhtari and K. Pourabdollah, Supramol. Chem., 23, 696 (2011).
S. Seyhan, M. Merdivan and N. Demirel, J. Hazard. Mater., 152, 79 (2008).
O. Bechiri, F. Ismail, M. Abbessi and M. E. H. Samar, J. Hazard. Mater., 152, 895 (2008).
M. Chiha, O. Hamdaoui, A. F. Chekkat and C. Pétrier, Ultrason. Sonochem., 17, 318 (2010).
M. S. Gasser, N. E. El-hefny and J. A. Daoud, J. Hazard. Mater., 151, 610 (2008).
B. Hamzah, N. Jalaluddin, A.W. Wahab and A. Upe, E. J. Chem., 7, 239 (2010).
B. Sengupta, R. Sengupta and N. Subrahmanyam, Hydrometallurgy, 84, 43 (2006).
C. Das, M. Rungta, G. Arya, S. DasGupta and S. De, J. Hazard. Mater., 159, 365 (2008).
M. Rajasimman, R. Sangeetha and P. Karthik, J. Chem. Eng., 150, 275 (2009).
Miesiac, K. Schüger and J. Szymanowski, J. Radioanal. Nucl. Chem., 163, 181 (1992).
P. S. Kulkarni, S. Mukhopadhyay, M. P. Bellary and S. K. Ghosh, Hydrometallurgy, 64, 49 (2002).
Kumbasar, J. Hazard. Mater., 178, 875 (2010).
P. S. Kulkarni and V.V. Mahajani, J. Membr. Sci., 201, 123 (2002).
S. Saravanan, K.M. Meera Sheriffa Begum and N. Anantharaman, Technol. Metallurgy, 41, 333 (2006).
S. Nosrati, N. S. Jayakumar and M. A. Hashim, Desalination, 266, 286 (2011).
N. Othman, S. N. Zailani and N. Mili, J. Hazard. Mater., 198, 103 (2011).
S.M. Mousavi, S. Kiani, M. Razavi Farmad, A. Hemati and B. Abbasi, J. Dispersion Sci. Technol., 33, 123 (2012).
A. L. Ahmad, A. Kusumastuti, C. J. C. Derek and B. S. Ooi, Chem. Eng. J., 171, 870 (2011).
Rahul Kumar Goyal, N. S. Jayakumar and M. A. Hashim, Desalination, 278, 50 (2011).
B. Mokhtari and K. Pourabdollah, J. Chinese Chem. Soc., 59, 1058 (2012).
B. Mokhtari and K. Pourabdollah, Korean J. Chem. Eng., 29, 1788 (2012).
M. Lurdes, F. Gameiro, P. Bento, M. Rosinda, C. Ismael, M. Teresa, A. Reis and M. R. Carvalho Jorge, J. Membr. Sci., 293, 151 (2007).
B. Mokhtari and K. Pourabdollah, Desalination, 292, 1 (2012).
B. Xu and H. Y. Li, Adv. Mater. Res., 496, 411 (2012).
A. L. Ahmad, A. Kusumastuti, C. J.C. Derek and B. S. Ooi, Desalination, 287, 30 (2012).
H. Yaoqiang, Z. Ningsheng, Q. Chengtun, H. Fei and Y. Yongli, Can. J. Chem. Eng., 90, 120 (2012).
Kumbasar, J. Hazard. Mater., 167, 1141 (2009).
B. Mokhtari and K. Pourabdollah, J. Chinese Chem. Soc., 59, 1058 (2012).
J. A. Reyes-Aguilera, M. P. Gonzalez, R. Navarro, T. I. Saucedo and M. Avila-Rodriguez, J. Membr. Sci., 310, 13 (2008).
D. Melzner, J. Tilkowski, A. Mohrmann, W. Poppe, W. Halwachs and K. Schügerl, Hydrometallurgy, 13, 105 (1984).
G. Charlot, Dosages absorptiométriques des éléments minéraux, 182 (1978).
G. Charlot, Les réactions chimiques en solution aqueuse et caractérisation des ions, 257 (1983).
G. H. Jeffery, J. Bassett, J. Mendham and R. C. Denny, Text book Quantitative Chemical Analysis, Fifth Edition, VOGEL’S, 684 (1989).
Kumbasar, J. Membr. Sci., 325, 460 (2008).
M. T. A. Reis and J. M. R. Carvalho, J. Membr. Sci., 237, 97 (2004).
N. Leepipatpiboon, U. Pancharoen and P. Ramakul, Korean J. Chem. Eng., 30, 194 (2013).
S. Venkatesan and K.M. Meera Sheriffa Begum, Desalination, 236, 65 (2009).
E. O. Out, Thermochim. Acta, 329, 117 (1999).
Alonso, M. J. Almendral, M. D. Báez, M. J. Porras, F. López Lavín and C. García de María, Anal. Chim. Acta, 408, 129 (2000).
J. A. Reyes-Aguilera, M. P. Gonzalez, R. Navarro, T. I. Saucedo and M. Avila-Rodriguez, J. Membr. Sci., 310, 13 (2008).
J. Yang, J. Yang, M. Tang, C. Tang and W. Liu, Hydrometallurgy, 96, 342 (2009).
N. Song, W. Li and Q. Jia, Sep. Purif. Technol., 104, 64 (2013).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mokhtari, B., Pourabdollah, K. Emulsion liquid membrane for selective extraction of bismuth from nitrate medium. Korean J. Chem. Eng. 30, 1458–1465 (2013). https://doi.org/10.1007/s11814-013-0062-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-013-0062-3