Abstract
Carbon dioxide reforming of methane was investigated over LaNi1−x Cr x O3 perovskite catalysts which were prepared by the malic acid method. The respective perovskite catalysts were a single phase of perovskite oxide without impurity phases. Their reduction behavior was characterized by temperature programmed reduction. In the LaNi1−x Cr x O3 perovskite catalysts, the catalytic activities were closely related to the reduction behavior of the catalysts, and the partial substitution of Cr to the B-site of perovskite catalysts promoted stability against reduction. When the x values were lower than 0.4, the LaNi1−x Cr x O3 perovskite catalysts were decomposed to La2O3 and Ni and the decomposition of perovskite structure led to large coke deposition. When the x values were higher than 0.4, the LaNi1−x Cr x O3 perovskite catalysts showed reduced catalytic activity but became stable to reduction and coke formation in the reforming reaction.
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Kim, J., Kim, T., Yoo, J.W. et al. Carbon dioxide reforming of methane to synthesis gas over LaNi1−x Cr x O3 perovskite catalysts. Korean J. Chem. Eng. 29, 1329–1335 (2012). https://doi.org/10.1007/s11814-012-0057-5
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DOI: https://doi.org/10.1007/s11814-012-0057-5