Abstract
Mo1.0V0.4Te0.25Nb0.24O x catalyst was prepared by hydrothermal synthesis in a solution containing a drying control chemical additive (DCCA) such as propionic acid (PA) or formamide (FA). The performance of the prepared catalysts in propane oxidation for producing acrylic acid (AA) was improved because the catalyst showed an increase in both the activity and AA selectivity. The activity was increased due to an increase in the surface area and in the oxygen mobility. The AA selectivity was increased due to a decrease in the number of acidic sites, which were responsible for the unselective and deep oxidation of intermediates. The catalyst performance was degraded when excess amounts of DCCA were used in the preparation step because the surface area decreased, due to the residues of DCCA, and the surface density of acidic sites increased.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
M. M. Lin, Appl. Catal. A, 207, 1 (2001).
Y. Moro-oka and W. Ueda, Adv. Catal., 40, 233 (1994).
M. Lin, T. B. Desai, F.W. Kaiser and P. D. Klugherz, Catal. Today, 61, 223 (2000).
M. Ai, Catal. Today, 101, 389 (1986).
B. Deniau, J. M. M. Millet, S. Loridant, N. Christin and J. L. Dubois, J. Catal., 260, 30 (2008).
E. Balcells, F. Borgmeier, I. Grißtede, H.-G. Lintz and F. Rosowski, Appl. Catal. A, 266, 211 (2004).
P. Botella, E. García-González, J. M. L. Nieto and J. M. González-Calbet, Solid State Sci., 7, 507 (2005).
J. M. L. Nieto, P. Botella, B. Solsona and J. M. Oliver, Catal. Today, 81, 87 (2003).
B. Zhu, H. Li, W. Yang and L. Lin, Catal. Today, 93–95, 229 (2004).
H. Tsuji, K. Oshima and Y. Koyasu, Chem. Mater., 15, 2112 (2003).
X. Yi, X. Sun, X. Zhang, C. Huang, W. Weng and H. Wan, Catal. Comm., 10, 1591 (2009).
M. Florea, A.-S. Mamede, P. Eloy, V. I. Parvulescu and E. M. Gaigneaux, Catal. Today, 112, 139 (2006).
B.Y. Jo, E. J. Kim and S. H. Moon, Appl. Catal. A, 332, 257 (2007).
D. R. Ulrich, J. Non-Cryst. Solids, 100, 174 (1988).
D. M. Smith, R. Desphande, C. J. Brinker, in M. J. Hampden-Smith, W.G. Klemperer and C. J. Brinker, Mater. Res. Soc., 271, 553 (1992).
D. Vitry, Y. Morikawa, J. L. Dubois and W. Ueda, Appl. Catal. A, 251, 411 (2003).
X. J. Yang, R. M. Feng, W. J. Ji and C. T. Au, J. Catal., 253, 57 (2003).
J. M. Oliver, J. M. López Nieto and P. Botella, Catal. Today, 96, 241 (2004).
R. M. Feng, X. J. Yang, W. J. Ji, H.Y. Zhu, X. D. Gu, Y. Chen, S. Han and H. Hibst, J. Mol. Catal. A, 267, 245 (2007).
K. Oshihara, T. Hisano and W. Ueda, Top. Catal., 15, 153 (2001).
P. Botella, J. M. López Nieto, A. Martínez-Arias and B. Solsona, Catal. Lett., 74, 149 (2001).
P. Botella, J. M. López Nieto, B. Solsona, A. Mifsud and F. Márquez, J. Catal., 209, 445 (2002).
A. Celaya Sanfiz, T.W. Hansen, F. Girgsdies, O. Timpe, E. Rödel, T. Ressler, A. Trunschke and R. Schlögl, Top. Catal., 59, 19 (2008).
F. Ivars, B. Solsona, S. Hernández and J. M. López Nieto, Catal. Today, 149, 260 (2010).
H. Murayama, D. Vitry, W. Ueda, G. Fuchs, M. Anne and J. L. Dubois, Appl. Catal. A, 318, 137 (2007).
P. Beato, A. Blume, F. Girgsdies, R. E. Jentoft, R. Schlögl, O. Timpe, A. Trunschke, G. Weinberg, Q. Basher, F. A. Hamid, S. B.A. Hamid, E. Omar and L. Mohd Salim, Appl. Catal. A, 307, 137 (2006).
Q. Xie, L. Chen, W. Weng and H. Wan, J. Mol. Catal. A, 240, 191 (2005).
N. R. Shiju and V. V. Guliants, Catal. Comm., 9, 2253 (2008).
N. R. Shiju and V. V. Guliants, Appl. Catal. A, 356, 1 (2009).
K. Bruckman and J. Haber, Proceedings of the 10th International Congress on Catalysis, Budapest, Hungary, 741 (1993).
F. Cavani, M. Koutyrev and F. Trifiro, Catal. Today, 24, 365 (1995).
G. Centi and F. Trifiro, Proceedings of Conference on Catalysis of Science and Technology, Tokyo, 225 (1991).
W. Ueda and Y. Suzuki, Chem. Lett., 24, 541 (1995).
J. M. Oliver, J. M. López Nieto, P. Botella and A. Mifsud, Appl. Catal. A, 257, 67 (2004).
A. Celaya Sanfiz, T.W. Hansen, F. Girgsdies, O. Timpe, E. Rödel, T. Ressler, A. Trunschke and R. Schlögl, Top. Catal, 50, 19 (2008).
S. Royer, D. Duprez and S. Kaliaguine, Catal. Today, 112, 99 (2006).
H. X. Dai, C. F. Ng and C. T. Au, J. Catal., 189, 52 (2000).
H. M. Zhang, Y. Shimizu, Y. Teraoka, N. Miura and N. Yamazoe, J. Catal., 121, 432 (1990).
S. Kaliaguine, A. Van Neste, V. Szabo, J. E. Gallot, M. Bassir and R. Muzychuk, Appl. Catal. A, 209, 345 (2001).
J. M. Wu, H. P. Yang, Y. N. Fan, B. L. Xu and Y. Chen, J. Fuel Chem. Technol., 35, 684 (2007).
L. F. Liotta, M. Ousmane, G. Di Carlo, G. Pantaleo, G. Deganello, G. Marcì, L. Retailleau and A. Giroir-Fendler, Appl. Catal. A, 347, 81 (2008).
N. Katada, T. Miyamoto, H. A. Begum, N. Naito, M. Niwa, A. Matsumoto and K. Tsutsumi, J. Phys. Chem. B, 104, 5511 (2000).
Y. Wang, Q. Zhang, T. Shishido and K. Takehira, J. Catal., 209, 186 (2002).
X. Qinhua and Y. Aizhen, Prog. Crystal Growth and Charact., 21, 29 (1990).
V.N. Romnnnikov, V. M. Mastikhin, S. Hoèevar and B. Držaj, Zeolite, 3, 311 (1983).
M. A. Sainz, F. J. Serrano, J. Bastida and A. Caballero, J. Euro. Ceramic Soc., I7, 1277 (1997).
A. H. Boonstra, T. N. M. Bernards and J. J. T. Smits, J. Non-Cryst. Solids, 109, 141 (1989).
G. Orcel, L. L. Hench, I. Artaki, J. Jonas and T.W. Zerda, J. Non-Cryst. Solids, 105, 223 (1988).
T. Adachi and S. Sakka, J. Non-Crys. Solids, 99, 118 (1988).
G.W. Scherer, J. Non-Cryst. Solids, 100, 77 (1988).
T. Mizuno, H. Nagata and S. Manabe, J. Non-Cryst. Solids, 100, 236 (1988).
X. Tu, N. Furuta, Y. Sumida, M. Takahashi and H. Niiduma, Catal. Today, 117, 259 (2006).
P. Korovchenko, N. R. Shiju, A. K. Dozier, U. M. Graham, M. O. Guerrero-Pérez and V. V. Guliants, Top. Catal., 50, 43 (2008).
R. K. Grasselli, Catal. Today, 49, 141 (1999).
S. S. Kum, B.Y. Jo and S.H. Moon, Appl. Catal. A, 365, 79 (2009).
P. Concepción, P. Botella and J. M. L. Nieto, Appl. Catal. A, 278, 45 (2004).
M. Baca, A. Pigamo, J. L. Dubois and J. M. M. Millet, Catal. Comm., 6, 215 (2005).
P. Concepción, P. Botella and J. M. López Nieto, Appl. Catal. A, 278, 45 (2004).
W. Ueda, D. Vitry and T. Katou, Catal. Today, 99, 43 (2005).
D. Linke, D. Wolf, M. Baerns, O. Timpe, R. Schlögl, S. Zeyß and U. Dingerdissen, J. Catal., 205, 16 (2002).
B. Mitra, I. E. Wachs and G. Deo, J. Catal., 240, 151 (2006).
X. J. Yang, R. M. Feng, W. J. Ji and C. T. Au, J. Catal., 253, 57 (2008).
L. T. Weng and B. Delmon, Appl. Catal. A, 81, 141 (1992).
Y. Moro-oka, Appl. Catal. A, 181, 323 (1999).
T. Ushikubo, Catal. Today, 57, 339 (2000).
D. Vitry, Y. Morikawa, J. L. Dubois and W. Ueda, Top. Catal., 23, 47 (2003).
J. Holmberg, R. K. Grasselli and A. Andersson, Top. Catal., 23, 55 (2003).
R. K. Grasselli, Catal. Today, 99, 23 (2005).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kum, S.S., Park, Y.S. & Moon, S.H. Improved performance of Mo-V-Te-Nb-O x catalysts prepared from a solution containing drying control chemical additives in propane oxidation to acrylic acid. Korean J. Chem. Eng. 28, 1364–1371 (2011). https://doi.org/10.1007/s11814-010-0528-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-010-0528-5