Abstract
We calculate the thermal expansion α p , isothermal compressibility κ T and the specific heat, C p -C v , as a function of pressure using the observed V-P data at room temperature close to the III–IV phase transition in CCl4. Calculated κ T , α p and C p -C v decrease as the pressure increases from phase III to phase IV in this molecular crystal system, as expected. On the basis of our calculations of the κ T , α p and C p -C v , the Pippard relations are established close to the III–IV phase transition in CCl4, which can be verified experimentally.
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Yurtseven, H., Dildar, Y. Calculation of thermodynamic quantities for carbon tetrachloride (CCl4) close to the III–IV phase transition. Korean J. Chem. Eng. 28, 252–255 (2011). https://doi.org/10.1007/s11814-010-0320-6
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DOI: https://doi.org/10.1007/s11814-010-0320-6