Abstract
The recovery of dilute acetic acid, which is widely found as a by-product in many chemical and petrochemical industries, becomes an important issue due to economic and environmental awareness. In general, separation of acetic acid in aqueous solution by conventional distillation columns is difficult, requiring a column with many stages and high energy consumption. As a result, the primary concern of the present study is the application of reactive distillation as a potential alternative method to recover dilute acetic acid. The direct use of dilute acetic acid as reactant for esterification with butanol to produce butyl acetate in the reactive distillation is investigated. Simulation studies are performed in order to investigate effect of the concentration of dilute acetic acid and key process parameters on the performance of the reactive distillation in terms of acetic acid conversion and butyl acetate production. In addition, three alternative control strategies are studied for the closed loop control of the reactive distillation. The control objective is to maintain the butyl acetate in a bottom product stream at the desired purity of 99.5 wt%.
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Arpornwichanop, A., Wiwittanaporn, C., Authayanun, S. et al. The use of dilute acetic acid for butyl acetate production in a reactive distillation: Simulation and control studies. Korean J. Chem. Eng. 25, 1252–1266 (2008). https://doi.org/10.1007/s11814-008-0207-y
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DOI: https://doi.org/10.1007/s11814-008-0207-y