Abstract
A solid-solution-phase Ba1.75Ca1.25MgSi2O8: Eu2+, Mn2+ phosphor in the photosynthetic action spectrum with dual band emissions at 438 nm and 660 nm is fabricated. X-ray diffraction (XRD) confirms the presence of the solid-solution phase. With the supporting information from the diffuse reflection spectrum, a feasible way to obtain higher energy-transfer (ET) efficiency is attained, and the ET efficiency of Eu2+-Mn2+ is enhanced to 76%. The mechanism of this enhancement is owing to variation of the solid solution composition of Ca3MgSi2O8 and Ba3MgSi2O8, which contributes to the extension of the critical distance. Temperature-dependent results show an enhancement which is attributed to Ca. These enhancements show great promise for improving eco-lighting devices.
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This work has been supported by the National Natural Science Foundation of China (No.21076161).
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Song, J., Sun, L., Li, J. et al. Luminescence properties of a solid solution typed (Ba,Ca)3MgSi2O8: Eu2+, Mn2+ phosphor with a 660 nmfeatured photosynthetic action spectrum. Optoelectron. Lett. 10, 343–346 (2014). https://doi.org/10.1007/s11801-014-4055-1
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DOI: https://doi.org/10.1007/s11801-014-4055-1