Abstract
Nanocomposite polymer electrolytes based on polyethylene glycol diacrylate and 1 M LiBF4 solution in γ-butyrolactone with addition of SiO2 nanoparticles were synthesized and studied. Resistance measurement at the Li/electrolyte and Li/nanocomposite electrolyte interface by the time-resolved electrochemical impedance showed its significant decrease in the presence of SiO2 nanoparticles. Charge-discharge cycling of prototypes of Li/LiFePO4 batteries for 50 cycles also showed the advantage of using nanocomposite polymer electrolytes over electrolytes without SiO2 additives.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1648–1654, September, 2018.
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Baymuratova, G.R., Slesarenko, A.A., Yudina, A.V. et al. Conducting properties of nanocomposite polymer electrolytes based on polyethylene glycol diacrylate and SiO2 nanoparticles at the interface with a lithium electrode. Russ Chem Bull 67, 1648–1654 (2018). https://doi.org/10.1007/s11172-018-2272-7
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DOI: https://doi.org/10.1007/s11172-018-2272-7