Abstract
Cobalt and aluminum hydroxo compounds with the hydrotalcite-type structure containing nitrate, carbonate, and hydroxyl groups are formed due to the deposition by precipitation of cobalt cations from a nitrate solution on δ- and γ-Al2O3 under the conditions of urea hydrolysis. The influence of the method of preparation on the anionic composition of the hydroxo compounds (precursors of the Co-Al catalyst) was studied. A correlation between the anionic composition of the precursor compound and the catalytic properties of the catalysts in the Fischer-Tropsch synthesis was established.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1796–1803, September, 2011.
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Simentsova, I.I., Khassin, A.A., Filonenko, G.A. et al. Anionic composition of precursors of the Co/Al2O3 catalysts for the Fischer-Tropsch synthesis. Russ Chem Bull 60, 1827–1834 (2011). https://doi.org/10.1007/s11172-011-0276-7
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DOI: https://doi.org/10.1007/s11172-011-0276-7