Summary
The thermodynamic data for NZP compounds MZr2(PO4)3 (M=Na, K, Rb, Cs, Zr0.25) and Na5D(PO4)3 (D=Ti, Zr) are reported. The heat capacities of the phosphates were measured between T=7 and T=640 K. The standard enthalpies entropies, and Gibbs functions of formation at T=298.15 K were derived. The obtained thermodynamic characteristics of phosphates of the NZP type structure and literature data are summarized. Thermodynamic functions of reactions of solid-state synthesis were calculated and the usability of ceramic technology for obtaining NZP compounds was proved.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Pet’kov, V., Asabina, E., Markin, A. et al. Thermodynamic data of the NZP compounds family. J Therm Anal Calorim 80, 695–700 (2005). https://doi.org/10.1007/s10973-005-0716-4
Issue Date:
DOI: https://doi.org/10.1007/s10973-005-0716-4