Abstract
As the global environmental problems of energy shortage and pollution are becoming prominent, the trend of using natural fibers as the reinforcement in the composite is increasing. In this study, the hemp fiber mat-reinforced polylactic acid (PLA) composite was designed and fabricated. As the fiber and matrix have different water affinity, the plasma treatment was used to improve the interfacial properties between them. After plasma treatment, scanning electron microscope (SEM), water contact angle and X-ray photoelectron spectroscopy (XPS) detection were conducted, and the results showed the effectiveness of plasma treatment. To further improve the interfacial properties and impart the electromagnetic shielding to the composites, the graphite and carbon black were respectively added into the interface by the spraying method. The results showed that the composite in which the fiber mat was plasma treated and 10wt% graphite added had the highest bending strength, and the after-fracture morphology of this composite showed good damage resistance. The reason lies in the synergistic effect from the combination of graphite and plasma treatment. Additionally, the electromagnetic shielding effectiveness of the above composite had the highest value of 20.25 dB in X-band frequency range.
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Viscusi G, Liparoti S, Pantani R, Barra G, Gorrasi G (2022) A layer-by-layer approach based on APTES/Cloisite to produce novel and sustainable high performances materials based on hemp fiberboards. Polym Degrad Stab 198:109892. https://doi.org/10.1016/j.polymdegradstab.2022.109892
Dhondt F, Muthu SS (2021) The future of hemp in the fashion industry. In: Dhondt Fieke, Muthu Subramanian Senthilkannan (eds) Hemp and Sustainability. Springer Singapore, Singapore, pp 109–123. https://doi.org/10.1007/978-981-16-3334-8_8
Li M, Pu YQ, Thomas VM et al (2020) Recent advancements of plant-based natural fiber-reinforced composites and their applications. Compos B Eng 200:108254. https://doi.org/10.1016/j.compositesb.2020.108254
Rashid ME, Khan MR, Ul Haque R, Hasanuzzaman M (2023) Challenges of textile waste composite products and its prospects of recycling. J Mater Cycles Waste Manag 25(3):1267–1287. https://doi.org/10.1007/s10163-023-01614-x
Partha P, Vijay C (2021) Moving towards the era of bio fibre based polymer composites. Clean Eng Technol 4:100182. https://doi.org/10.1016/j.clet.2021.100182
Müssig J, Amaducci S, Bourmaud A, Beaugrand J, Shah DU (2020) Transdisciplinary top-down review of hemp fibre composites: from an advanced product design to crop variety selection. Compos Part C: Open Access 2:100010. https://doi.org/10.1016/j.jcomc.2020.100010
Ahmed A, Islam MZ, Mahmud MS, Sarker ME, Islam MR (2022) Hemp as a potential raw material toward a sustainable world: a review. Heliyon 8(1):e08753. https://doi.org/10.1016/j.heliyon.2022.e08753
Deshmukh GS (2022) Advancement in hemp fibre polymer composites: a comprehensive review. J Polym Eng 42:575–598. https://doi.org/10.1515/polyeng-2022-0033
Siakeng R, Jawaid M, Ariffin H, Sapuan SM, Asim M, Saba N (2019) Natural fiber reinforced polylactic acid composites: a review. Polym Compos 40:446–463. https://doi.org/10.1002/pc.24747
Sahayaraj AF, Muthukrishnan M, Ramesh M (2022) Experimental investigation on physical, mechanical, and thermal properties of jute and hemp fibers reinforced hybrid polylactic acid composites. Polym Compos 43:2854–2863. https://doi.org/10.1002/pc.26581
Sepe R, Bollino F, Boccarusso L, Caputo F (2018) Influence of chemical treatments on mechanical properties of hemp fiber reinforced composites. Compos Part B-Eng 133:210–217. https://doi.org/10.1016/j.compositesb.2017.09.030
Gholampour A, Ozbakkaloglu T (2020) A review of natural fiber composites: properties, modification and processing techniques, characterization, applications. J Mater Sci 55:829–892. https://doi.org/10.1007/s10853-019-03990-y
Behera S, Gautam RK, Mohan S, Chattopadhyay A (2021) Hemp fiber surface modification: Its effect on mechanical and tribological properties of hemp fiber reinforced epoxy composites. Polym Compos 42:5223–5236. https://doi.org/10.1002/pc.26217
Behera S, Gautam RK, Mohan S (2022) Polylactic acid and polyhydroxybutyrate coating on hemp fiber: its effect on hemp fiber reinforced epoxy composites performance. J Compos Mater 56:929–939. https://doi.org/10.1177/00219983211066991
Behera S, Gautam RK, Mohan S (2022) The effect of eco-friendly chemical treatment on sisal fiber and its epoxy composites: thermal, mechanical, tribological and morphological properties. Cellulose 29:9055–9072. https://doi.org/10.1007/s10570-022-04826-w
Gibeop N, Lee DW, Prasad CV, Toru F, Kim BS, Song JI (2013) Effect of plasma treatment on mechanical properties of jute fiber/poly (lactic acid) biodegradable composites. Adv Compos Mater 22:389–399. https://doi.org/10.1080/09243046.2013.843814
Wang J, Chen P, Lu C, Yu Q, Li W, Ren R (2018) Improvement of aramid fiber III reinforced bismaleimide composite interfacial adhesion by oxygen plasma treatment. Compos Interface 25:771–783. https://doi.org/10.1080/09276440.2018.1439630
Brunengo E, Conzatti L, Utzeri R et al (2019) Chemical modification of hemp fibres by plasma treatment for eco-composites based on biodegradable polyester. J Mater Sci 54:14367–14377. https://doi.org/10.1007/s10853-019-03932-8
Barbiere R, Touchard F, Chocinski-Arnault L, Fourre E, Leroy E, Barrault J (2021) Characterisation of interfacial adhesion in hemp composites after H2O2 and non-thermal plasma treatments. J Compos Mater 55:3751–3762. https://doi.org/10.1177/00219983211015427
Mohammed M, Rasidi MSM, Mohammed AM et al (2022) interfacial bonding mechanisms of natural fibre-matrix composites: an overview. BioResources 17:7031–7090. https://doi.org/10.15376/biores.17.4.Mohammed
Gupta US, Tiwari S, Sharma U (2023) The effect of cold glow discharge nitrogen plasma treatment of sisal fiber (Agave Sisalana) on sisal fiber reinforced epoxy composite. Pigm Resin Technol. https://doi.org/10.1108/prt-02-2023-0019
Dai XY, Du YZ, Yang JY et al (2019) Recoverable and self-healing electromagnetic wave absorbing nanocomposites. Compos Sci Technol 174:27–32. https://doi.org/10.1016/j.compscitech.2019.02.018
Zhang HT, Lin SD (2023) Research progress with membrane shielding materials for electromagnetic/radiation contamination. Membranes 13(3):315–360. https://doi.org/10.3390/membranes13030315
Yousefi N, Sun XY, Lin XY et al (2014) Highly aligned graphene/polymer nanocomposites with excellent dielectric properties for high-performance electromagnetic interference shielding. Adv Mater 26:5480–5487. https://doi.org/10.1002/adma.201305293
Thomassin JM, Jérôme C, Pardoen T, Bailly C, Huynen I, Detrembleur C (2013) Polymer/carbon based composites as electromagnetic interference (EMI) shielding materials. Mater Sci Eng R-Rep 74:211–232. https://doi.org/10.1016/j.mser.2013.06.001
Liu S, Qin SH, Jiang Y, Song PA, Wang H (2021) Lightweight high-performance carbon-polymer nanocomposites for electromagnetic interference shielding. Compos Part a-Appl S 145(45):106376. https://doi.org/10.1016/j.compositesa.2021.106376
Abbasi H, Antunes M, Velasco JI (2019) Recent advances in carbon-based polymer nanocomposites for electromagnetic interference shielding. Prog Mater Sci 103:319–373. https://doi.org/10.1016/j.pmatsci.2019.02.003
Yue JW, Feng YY, Qin MM, Feng W (2023) Carbon-based materials with combined functions of thermal management and electromagnetic protection: preparation, mechanisms, properties, and applications. Nano Res 17(3):883–903. https://doi.org/10.1007/s12274-023-6257-y
Lee JH, Kim YS, Ru HJ, Lee SY, Park SJ (2022) Highly flexible fabrics/epoxy composites with hybrid carbon nanofillers for absorption-dominated electromagnetic interference shielding. Nano-Micro Lett 14(1):188–204. https://doi.org/10.1007/s40820-022-00926-1
Ghosh S, Mondal S, Ganguly S, Remanan S, Singha N, Das NC (2018) Carbon nanostructures based mechanically robust conducting cotton fabric for improved electromagnetic interference shielding. Fiber Polym 19:1064–1073. https://doi.org/10.1007/s12221-018-7995-4
Kim Y-S, Lee J-H, Park S-J (2021) Effect of ambient plasma treatment on single-walled carbon nanotubes-based epoxy/fabrics for improving fracture toughness and electromagnetic shielding effectiveness. Compos Part a-Appl S 148:106456. https://doi.org/10.1016/j.compositesa.2021.106456
Abdel-Fattah E (2019) Surface and thermal characteristics relationship of atmospheric pressure plasma treated natural luffa fibers. Eur Phys J D 73:1–8. https://doi.org/10.1140/epjd/e2019-90281-3
Marinho B, Ghislandi M, Tkalya E, Koning CE, de With G (2012) Electrical conductivity of compacts of graphene, multi-wall carbon nanotubes, carbon black, and graphite powder. Powder Technol 221:351–358. https://doi.org/10.1016/j.powtec.2012.01.024
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The authors gratefully acknowledge Shanghai Frontiers Science Center of Advanced Textiles.
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Yao, L., Liu, H., Ren, D. et al. Effect of plasma treatment and graphite/carbon black addition on bending and electromagnetic shielding of hemp fiber/polylactic acid composites. J Mater Sci (2024). https://doi.org/10.1007/s10853-024-10214-5
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DOI: https://doi.org/10.1007/s10853-024-10214-5