Abstract
12-Phosphotungstic acid and its cesium salts supported on a dealuminated ultra-stable Y zeolite were prepared, and showed the high catalytic activity in the liquid-phase esterification of acetic acid with n-butanol. The supported Cs2.5H0.5PW12O40 catalyst gave a high conversion of n-butanol of 94.6% and a selectivity for n-butyl acetate of 100%, accompanying the high water-tolerance and catalytic reusability without regeneration.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
M. Misono (1987) Catal. Rev. Sci. Eng. 29 269
Y. Izumi, M. Ogawa, W. Nohara and K. Urabe, Chem. Lett. (1992) 1987.
J. Kaur and I.V. Kozhevnikov, Chem. Commun. (2002) 2508.
I.V. Kozhevnikov K.R. Kloetstra A. Sinnema H.W. Zandbergen H. Bekkum Particlevan (1996) J. Mol. Catal. A 114 287 Occurrence Handle10.1016/S1381-1169(96)00328-7
S.R. Mukai L. Lin T. Masuda K. Hashimoto (2001) Chem. Eng. Sci. 56 779 Occurrence Handle10.1016/S0009-2509(00)00289-X
F. Marme G. Coudurier J.C. Védrine (1998) Micropor. Mesopor. Mater. 22 151 Occurrence Handle10.1016/S1387-1811(98)00089-4
N. Nowinska R. Fiedorov J. Adamiec (1991) J. Chem. Soc., Faraday Trans. 87 749
M.E. Chimienti L.R. Pizzio C.V. Cáceres M.N. Blanco (2001) Appl. Catal. A 208 7 Occurrence Handle10.1016/S0926-860X(00)00702-X
I.V. Kozhevnikov A. Sinnema R.J.J. Janse K. Pamin H. Bekkum Particlevan (1995) Catal. Lett. 30 241 Occurrence Handle10.1007/BF00813690
Q.Y. Liu W.L. Wu J. Wang Y.R. Wang X.Q. Ren (2004) Micropor. Mesopor. Mater. 76 51 Occurrence Handle10.1016/j.micromeso.2004.08.001
S.R. Mukai M. Shimoda L. Lin H. Tamon T. Masuda (2003) Appl. Catal. A 256 107 Occurrence Handle10.1016/S0926-860X(03)00392-2
B. Sulikowski R. Rachwalik (2003) Appl. Catal. A 256 173 Occurrence Handle10.1016/S0926-860X(03)00397-1
B. Sulikowski J. Haber A. Kubacka K. Pamin Z. Olejniczak J. Ptaszyński (1996) Catal. Lett. 39 27
S.R. Mukai T. Masuda I. Ogino K. Hashimoto (1997) Appl. Catal. A 165 219 Occurrence Handle10.1016/S0926-860X(97)00203-2
N. Mizuno M. Misono (1998) Chem. Rev. 98 199 Occurrence Handle10.1021/cr960401q Occurrence Handle11851503
S. Soled S. Miseo G. McVicker W.E. Gates A. Gutierrez J. Paes (1997) Catal. Today 36 441 Occurrence Handle10.1016/S0920-5861(96)00235-0
Y. Izumi K. Urabe M. Onaka (1998) Micropor. Mesopor. Mater. 21 227 Occurrence Handle10.1016/S1387-1811(98)00029-8
Y. Izumi, M. Ono, M. Ogawa and K. Urabe, Chem. Lett. (1993) 825
J. Wang Z. Lin S.Y. Han M.S. Eum C.W. Lee (2003) J. Ind. Eng. Chem. 9 281
J. Wang D.M. Jiang J.O. Baeg C.W. Lee (2004) J. Ind. Eng. Chem. 10 454
J. Wang H. Zhu (2004) Catal. Lett. 93 209 Occurrence Handle10.1023/B:CATL.0000017078.26948.b4
T. Okuhara T. Nishimura H. Watanabe M. Misono (1992) J. Mol. Catal. 74 247 Occurrence Handle10.1016/0304-5102(92)80242-9
T. Nakato M. Kimura S. Nakata T. Okuhara (1998) Langmuir 14 319 Occurrence Handle10.1021/la970867j
J. Lynch F. Raatz P. Dufresne (1987) Zeolites 7 333 Occurrence Handle10.1016/0144-2449(87)90036-4
I.V. Kozhevnikov K.R. Kloetstra A. Sinnema H.W. Zandbergen H. Bekkum Particlevan (1996) J. Mol. Catal. A 114 287 Occurrence Handle10.1016/S1381-1169(96)00328-7
N. Essayem G. Coudurier M. Fournier J.C. Védrine (1995) Catal. Lett. 34 223
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhang, FM., Wang, J., Yuan, CS. et al. A pronounced catalytic activity of heteropoly compounds supported on dealuminated USY for liquid-phase esterification of acetic acid with n-butanol. Catal Lett 102, 171–174 (2005). https://doi.org/10.1007/s10562-005-5851-9
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s10562-005-5851-9