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,4′′,4′′′-tetrasulfonato-phthalocyanine/N-butyl-N′-methylanthraquinone-4,4′-bipyridinum dibromide assembly (ZnTsPc-V-AQ), was observed to be enhanced by ten times when the sample was optically pumped by a 355 nm pump beam. The enhancement of the nonlinearity was found to be due predominantly to the charge transfer between the two monomers of the supramolecule after optical excitation.
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Received: 2 July 1996
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Si, J., Wang, Y., Yang, Q. et al. Charge-separated-state enhancement of the third-order optical nonlinearity of a photosensitizer-electron acceptor triad assembly . Appl Phys B 64, 663–665 (1997). https://doi.org/10.1007/s003400050230
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DOI: https://doi.org/10.1007/s003400050230