Summary
The simplest experimental method to determine the Hansen Solubility Parameters (HSP) for a polymer is to evaluate whether or not it dissolves in selected solvents. The solvents dissolve the polymer have HSP closer to it than those which don’t. Then a computer program can be used to find the HSP of the selected polymer. In this work, the effect of calculation method on the values of HSP has been analyzed completely. The results show that optimization method for calculation of HSP is an important factor in the precision of obtained values of these parameters.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
Hildebrand JH, Scott RL, (1964) Solubility of Non-Electrolytes. 3rd ed., Reinhold, New York, Dover, New York
Hildebrand JH, Scott RL, (1962) Regular Solutions. Prentice-Hall, Englewood Cliffs, NJ
Hildebrand JH, Scott RL, (1970) Regular and Related Solutions. Van Nostrand-Reinhold, Princeton, NJ
Van Arkel AE, (1946) Trans. Faraday Soc., 42B:81
Small PA (1953) J. Appl. Chem. 3:71
Anderson R (1961) Ph.D. thesis, Dept. of Chemical Engineering, University of California, Berkeley
Blanks RF, Prausnitz JM, (1964) Ind. Eng. Chem. Fundam., 3:1
Pausnitz, JM, Anderson R., (1961) Am. Inst. Chem. Eng. J., 7:96
Weimer RF, Prausnitz JM, (1965) Hydrocarbon Proc. Petr. Ref., 44:237
Prausnitz JM, Shair FH (1961) Am. Inst. Chem. Eng. J. 7:682
Hansen CM (1967) J. Paint Technol. 39:104
Hansen CM (1967) J. Paint Technol. 39:505
Hansen CM, Skaarup K (1967) J. Paint Technol. 39:511
Hansen CM, (1967) The Three-Dimensional Solubility Parameter and Solvent Diffusion Coefficient, Danish Technical Press, Copenhagen, Denmark
Hansen CM, (2000) Hansen Solubility Parameters: A User’s Handbook, CRC Press, Boca Raton, Florida
Harrington EC Jr, (1965) Ind. Qual. Control, 21:494
Lagarias JC, Reeds JA, Wright MH, Wright PE, (1998) SIAM J. Optim., 9:112
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Gharagheizi, F., Sattari, M. & Angaji, M. Effect of Calculation Method on Values of Hansen Solubility Parameters of Polymers. Polym. Bull. 57, 377–384 (2006). https://doi.org/10.1007/s00289-006-0568-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00289-006-0568-5