Abstract
Thev 6 vibration-rotational band of13CH3F has been measured in the range 1070–1260 cm−1 using a Fourier-transform spectrometer with unapodized resolution 0.0027 cm−1. The wavenumbers of 1262 vibration-rotational transitions to thev 6=1 (E) vibrational state have been assigned and fitted by least squares with the standard deviation of the fit 1.31×10−4 cm−1. This made it possible to determine 19 spectroscopical parameters of thev 6=1 state including parameters of the Δk=±2, Δl=∓2 and Δk=±4, Δl=∓2 interactions leading to theA 1−A 2 splittings of many rotational levels withkl=+1 andkl=−2.
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Dedicated to Professor István Kovács on his eightieth birthday
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Papoušek, D., Hsu, YC., Klee, S. et al. High-resolution Fourier-transform infrared spectrum of the13CH3F fundamental band of13CH3F. Acta Physica Hungarica 74, 419–426 (1994). https://doi.org/10.1007/BF03156415
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DOI: https://doi.org/10.1007/BF03156415