Abstract
Adsorption characteristics of 2,4-Dichlorophenoxyacetic acid (2,4-D) and 2,4-Dinitrophenol (2,4-DNP) onto granular activated carbon (GAC) were studied to obtain basic information on their removal from aqueous solution. Single component adsorption equilibria of 2,4-D and 2,4-DNP dissolved in water have been measured for three kinds of GACs (F400, SLS103, and WWL). In case of 2,4-D, the magnitude of adsorption capacity was in the order of F400> SLS103>WWL, and that for 2,4-DNP was SLS103> F400> WWL. The influence of temperature and initial pH of aqueous solution on adsorption has been discussed in detail by using the Sips equation.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
Buckingham, J., “Dictionary of Organic Compounds,” 5th Ed. and Supplements, Chapman and Hall, New York,2, 2275 (1988).
Chen, J. P. and Wang, X., “Removing Copper, Zinc, and Lead Ion by Granular Activated Carbon in Pretreated Fixed-bed Columns,”Sep. & Purifi. Tech.,19, 157 (2000).
Do, D. D., Adsorption analysis: “Equilibria and Kinetics,” Series on Chemical Engineering, Imperial College Press,2 (1998).
EPA Health Effects Notebook for Hazardous Air Pollutants-Draft.
Hornsby, A. G., Wauchope, R. D. and Herner, A. E., “Pesticide Properties in the Environment,” Springer-Verlag New York, Inc. (1996).
Hsieh, C. T. and Teng, H., “Influence of Mesopore Volume and Adsorbate Size on Adsorption Capacities of Activated Carbons in Aqueous Solutions,”Carbon,38, 863 (2000).
Khan, A. R., Ataullah, R. and Al-Haddad, A., “Equilibrium Adsorption Studies of Some Aromatic Pollutants from Dilute Aqueous Solutions on Activated Carbon at Different Temperatures,”J. Colloid Interface Sci.,194, 154 (1997).
Kim, S.H., Bidkar, A., Ngo, H.H., Vigneswaran, S. and Moon, H., “Adsorption and Mass Transfer Characteristics of Metsulfuron-Methyl on Activated Carbon,”Korean J. Chem. Eng.,18, 163 (2001).
Ko, J.Y., “Adsorption and Desorption of cHlorophenols Onto Nonionic Polymeric Sorbents,” MS thesis, Department of Chemical Technology, Chonnam National University (2001).
Lee, D. H. and Moon, H., “Adsorption Equilibrium of Heavy Metals on Natural Zeolites,”Korean J. Chem. Eng.,18, 247 (2001).
Mangat, S. S. and Elefsiniotis, P., “Biodegradation of the Herbicid 2,4-dichlorophen-oxyacetic acid (2,4-D) in Sequencing Batch Reactors,”Wat. Res.,33, 861 (1999).
Markovska, L., Meshko, V. and Noveski, V., “Adsorption of Basic Dyes in a Fixed Bed Column,”Korean J. Chem. Eng.,18, 190 (2001).
Moon, J.K., Keum, D.K. and Lee, W.K., “Adsorption Equilibria for m-cresol, Quinoline, and 1-naphthol oNto Silica Gel,”Korean J. Chem. Eng.,6, 172 (1989).
Na, B.K., Koo, K.K., Eum, H. M., Lee, H. and Song, H.K., “CO2 Recovery from Flue Gas by PSA Process using Activated Carbon,”Korean J. Chem. Eng.,18, 220 (2001).
Noll, K. E., Gounaris, V. and Hou, W. S., “Adsorption Technology for Air and Water Pollution Control,” Lewis Publishers (1992).
Oh, K. H. and Kim, Y. S., “Biodegradation of the Commercial Phenoxy Herbicide 2,4-D by Microbial Consortium,”Korea J. Biotechnol. Bioeng.,9, 469 (1994).
Radke, C. J. and Prausnitz, J.M., “Adsorption of Organic Solutes for Dilute Aqueous Solution on Activated Carbon,”Ind. Eng. Chem. Fund,11, 445 (1972).
The Merck Index. “An Encyclopedia of Chemicals, Drugs, and Biologicals,” 11th. Ed. S. Budavari. Merck and Co. Inc., Rahway, NJ (1989).
Toth, J., “Application of Toth’s Equation to Describe the Single-solute Adsorption from Dilute Solutions on Solids,”J. Colloid Interface Sci.,94, 573 (1983).
Vroumsia, T., Steiman, R., Seigle-Murandi, F. and Benoit-Guyod, J. L., “Effects of Culture Parameters on the Degradation of 2,4-Dichlorophenoxyacetic Acid (2,4-D) and 2,4-Dichlorophenol (2,4-DCP) by Selected Fungi,”Chemosphere,39, 1397 (1999).
Wong, P. K., “Effects of 2,4-D, Glyphosate and Paraquat on Growth, Photosynthesis and Chlorophyll-a Synthesis of Scenedesmus Quadricauda Berb 614,”Chemosphere,41, 177 (2000).
Zumriye, A. and Julide, Y., “A Comparative Adsorption/biosorption Study of Mono-chlorinated Phenols Onto Various Sorbents,”Waste Management,21, 695 (2001).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kim, S.J., Shim, W.G., Kim, T.Y. et al. Adsorption equilibrium characteristics of 2,4-Dichlorophenoxyacetic acid and 2,4-Dinitrophenol on granular activated carbons. Korean J. Chem. Eng. 19, 967–977 (2002). https://doi.org/10.1007/BF02707219
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02707219