Abstract
Thermally and mechanically enhanced nanoporous silica-polyurethane hybrid aerogel was synthesized by sol-gel processing and low temperature supercritical CO2 drying. A partially condensed silica solution and a polymeric MDI were used as the raw materials with a tertiary amine as a catalyst and 1,4-dioxiane as a dilution solvent. After the gelation reaction was completed, aged wet hybrid aerogel was dried by a low temperature supercritical CO2 drying technique. Also, thermophysical characteristics such as density, BET surface area, and thermal conductivity as a function of catalyst ratio and aging time of the synthesized hybrid aerogel were analyzed. It was found that, at a fixed target density, the lowest average pore size of the aerogel, 8 nm, was obtained when the catalyst ratio was 0.1 wt.%. Also, at these conditions, the BET surface area showed the highest surface area, 287.3 m2/g. It was found that with decreasing average pore size and with increasing BET surface area, thermal conductivity tends to decrease. At pressure 1 torr, the sample aerogel showed the lowest thermal conductivity, 0.0184 W/mK.
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Yim, TJ., Kim, S.Y. & Yoo, KP. Fabrication and thermophysical characterization of nano-porous silica-polyurethane hybrid aerogel by sol-gel processing and supercritical solvent drying technique. Korean J. Chem. Eng. 19, 159–166 (2002). https://doi.org/10.1007/BF02706890
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DOI: https://doi.org/10.1007/BF02706890