Abstract
This review covers the literature on sesamin, sesamolin and related compounds published since 1951. The topics reviewed include structural con-siderations, natural occurrence, influence of oil processing, analytical methods, isolation proce-dures and commercial preparations, various bio-logical effects and stability questions.
Recent developments in pyrethrum synergists are discussed at length, since they owe so much to the discovery of the synergistic activities of sesamin and sesamolin.
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References
Budowski, P., and K. S. Markley, Chem. Rev.48, 125 (1951).
Beroza, M., and M. S. Schechter, J. Am. Chem. Soc.78, 1242 (1956).
Freudenberg, K., and E. Fischer, Naturwissenschaften43, 16 (1956). Chem. Ber.89, 1230 (1956).
Bruchhausen, F. V., and K. Lingner, Arch. Pharm. 290, 1 (1957).
Beroza, M., J. Am. Chem. Soc.78, 5082 (1956).
Freudenberg, K., and G. S. Sidhu, Tetrahedron Letters, No. 20, 3 (1960). Chem. Ber.94, 851 (1961).
Gurevich, A. I., M. N. Kolosoff and M. M. Shemyakin, Doklady Akad. Nauk. SSSR131, 833 (1960); C. A.54, 16442g (1960).
Carnmalm, B., H. Erdtman and Z. Pelchowicz, Acta Chem. Scand9, 1111 (1955); Erdtman, H. and Z. Pelchowicz, Chem. Ind. 567 (1955).
Govil, G., C. R. Kanekar and C. L. Khetrapal, Curr. Sci.30, 253 (1961).
Weinges, K., Chem. Ber.94, 2522 (1961).
Becker, E. D. and M. Beroza, Tetrahedron Letters, No. 4, 157 (1962).
Beroza, M., J. Am. Chem. Soc.77, 3332 (1955).
Haslam, E., and E. Haworth, J. Chem. Soc.1955, 827.
Boeseken, J., W. D. Cohen and C. Kip, Eec. trav. chim.55, 815 (1936).
Adriani, W., Z. Untersuch. Lebensm.56, 187 (1928).
Jones, W. A., M. Beroza and E. D. Becker, J. Org. Chem.27, 3232 (1962).
Erdtman, H., Colonial Research, London 1955/56; C. AS3 13582h (1959).
Carnmalm, B., and H. Erdtman, Chem. Ind. 570, (1955).
Antonaccio, L. D., and O. R. Gottlieb, Anais. Assoc. Brasil. Quim.18, 183 (1959); C. A.54, 11163h (1960).
Masumura, M., Nippon Kagaku Zasshi78, 1318 (1955) ; C. A.51, 17900e (1957).
Carnmalm, B., Acta Chem. Scand.10, 134 (1956).
Karyone, T., H. Kimura and I. Nakamura, Yakugaku Zasshi78, 1152 (1958); C. A.53, 5221d (1959).
Kimura, H., Japan. 8129 (1959); C. A.54, 3868d (1960).
Hollis, A. F., R. H. Prager, E. Ritchie and W. C. Taylor, Austr. J. Chem.14, 100 (1961).
Cameron, D. W., and M. D. Sutherland,Ibid 14, 135 (1961).
Hansel, B., and D. Zander, Arch. Pharm.294, 699 (1961).
Pearman, R. W., W. D. Raymond and J. A. Squires, Colonial Plant and Animal Prod. (London)2, 297 (1951) ; C. A.47, 6677i (1953).
Nagabhushanam, A., M. Srinivasan and V. Subrahmanyan, J. Sci. Ind. Res. (India)15C, 283 (1956); C. A.51, 7742g (1957).
Beroza, M., and M. L. Kinman, JAOCS32, 348 (1955).
Fujimura, K., and Y. Toyama, Abura Kagaku7, 31 (1958). Mem. Fac. Eng. Nagoya, Univers. (English); C. A. 52, 11444b (1958).
Bhide, P. J., and J. G. Kane, J. Sci. Ind. Bes. (India)12B, 68 (1953); C. A. 47, 7238g (1953).
Mathur, L. B., and K. S. Tilara, JAOCS30, 447 (1953).
Pavolini, L., and B. Isidoro, Olii minerali, grassi e saponi, colori e vernici29, 33 (1952); C. A.47, 2515a (1953).
Gulati, K. C, and A. E. S. Kartha, J. Sci. Ind. Res. (India)11B, 346 (1952); C. A.47, 126791 (1953).
Iyer, B. H., and N, L. Narayanamurthy, Oils and Oilseed J. (India)5, 98 (1953); C. A.48, 8978f (1954).
Mathur, L. B., E. Sahai and E. N. Mathur, J. Proc. Oil Technol. Assoc. (India) Kanpur8, 41 (1952) ; C. A.48, 9083g (1954).
Chakravarti, E. N., and S. Dash, Bull. Calcutta School Trop. Med.4, 165 (1956); C. A.51, 53211 (1957).
Polzella, L., Boll. lab. chim. provinciali (Bologna)9, 163 (1958) ; C. A.53, 6470i (1959).
Roy, S. C, A. R. Sen and R. K. Chatterjee, J. Proc Inst. Chemists (India)31, 16 (1959); C. A.54, 4004a (1960).
Daghetta, A., and O. Bruss, Ann. Sper. agrar. (Rome)11, No. 4 Suppl., 97 (1957); C. A.51, 18372e (1957).
Benassati, F., Ital. 575,723 (1958); C. A.55, 23376e (1961).
Pavolini, L., Olii minerali, grassi e saponi, colori e vernici14, 41 (1934); C. A.29, 2007 (1935).
Renko, P., Mondo latte 1952, 711,715; C. A.47, 4007a (1953).
Chindemi, A., Boll. lab. chim. provinciali (Bologna) 9, 297 (1958); C. A.53, 19415f (1959).
Daghetta, A., Olii minerali, grassi e saponi, colori e vernici34, 423 (1957); C. A.55, 18991a (1961).
Suarez, C. C, B. T. O’Connor, E. T. Field and W. G. Bickford, Anal. Chem.24, 668 (1952).
Budowski, P., E. T. O’Connor and E. T. Field, JAOCS27, 307 (1950).
Blum, M. S., J. Agr. Food Chem.3, 122 (1955).
Beroza, M., Anal. Chem.26, 1970 (1954).
Beroza, M., J. Agr. Food Chem.4, 53 (1956).
Beroza, M., Anal. Chem.26, 1173 (1954).
Beroza, M.,Ibid 28, 1550 (1956).
Beroza, M., J. Agr. Food Chem.11, 51 (1963).
Bhat, S. G., J. G. Kane and A. Sreenivasan, JAOCS33, 197 (1956).
Wachs, W., Z. Lebensm.-Untersuch. u. Forsch.96, 168 (1953). C. A.47, 6153g (1953).
Beroza, M., JAOCS31, 302 (1954).
Omohundro, A. L., E. C. Fanto and I. Reich, U.S. 2,467,903 (1949). C. A.43, 5151b (1949).
Omohundro, A. L., E. C. Fanto and I. Beich, U.S. 2,467,904 (1949). C. A.43, 5151c (1949).
Feinstem, L., and S. J. Ringel, U.S. 2,557,956 (1951). C. A.45, 9901d (1951).
Purdy, B. H., and J. A. Kneeland, U.S. 2,786,063 (1957). C. A.51, 9078a (1957).
Tracy, E. L., U.S. 2,837,534 (1958). C. A.52, 19004g (1958).
Takata Y. and T. Matsuda, J. Pharm. Soc. (Japan)74, 693 (1954). C. A.48, 10652h (1954).
Benassati, F., Ital. 572,305 (1958). C. A. 55, 23376e (1961).
Hardwicke, J. E., J. King and B. C. Terrell, U.S. 2,885,407 (1959). C. A. 55, 14268b (1961).
Beroza, M., J. Agr. Food Chem.4, 49 (1956).
Haller, H. L., F. B. LaForge and W. N. Sullivan, J. Econ. Entom.35, 247 (1942).
Gersdorff, W. A., B. H. Nelson and N. Mitlin,Ibid. 44, 921 (1951).
Eddy, G. W., M. M. Cole and G. S. Burden,Ibid 47, 501 (1954).
Endicott, J. L., U.S. 2,610,940 (1952); C. A.47, 265d (1953).
Omohundro, A. L., and F. M. Neumeier, U.S. 2,664,381 (1953) ; C. A.48, 4186h (1954).
Srivastava, A. S., and G. P. Awasthi, Proc. 10th Intern. Congr. Entom. Montreal1956, 2, 243 (Publ. 1958); C. A.54, 2647b (1960).
Gersdorff, W. A., P. G. Piquett and M. Beroza, J. Agr. Food Chem.4, 858 (1956).
Beroza, M., Soap Chem. Specialties32, 128,133,135,175 (1956).
Beroza, M., and W. F. Barthel, J. Agr. Food Chem.5, 855 (1957).
Gersdorff, W. A., P. G. Piquett and M. Beroza, J. Econ. Entom.50, 406 (1957).
Alexander, B. H., T. A. Oda, B. T. Brown and S. I. Gertler, J. Org. Chem.23, 1969 (1958).
Gertler, S. F., B. H. Alexander and M. Beroza,Ibid 24, 327 (1959).
Alexander, B. H., S. I. Gertler, B. T. Brown, T. A. Oda and M. Beroza,Ibid 24, 1504 (1959).
Alexander, B. H., S. I. Gertler, T. A. Oda, E. T. Brown, R. W. Ihudris and M. Beroza,Ibid 25, 626 (1960).
Kuraoka, T., S. Sugawara and A. Katsnyama, Nippon Kagaku Zasshi79, 1554 (1958); C. A.54, 4479d (1960).
Moore, B. P., and P. S. Hewlett, J. Sci. Food Agr. 9, 666 (1958).
Kerr, B. W., Australia Commonwealth Sci. Ind. Research Or- ganization, Bull. No.261, 32 (1951); C. A.46, 2227h (1952).
Gersdorff, W. A., N. Mitlin and M. Beroza, J. Econ. Entom.47, 839 (1954).
Beroza, M., U.S. 2,755,218 (1956); C. A.51, 2034a (1957).
Beroza, M., U.S. 2,755,219 (1956) ; C. A.50, 14172f (1956).
Beroza, M., U.S. 2,764,517 (1956); C. A.51, 1525c (1957).
Beroza, M., U.S. 2,832,792 (1958); C. A.52, 19001g (1958).
Gersdorff, W. A., P. G. Piquett and M. Beroza, J. Econ. Entom.50, 409 (1957).
Gersdorff, W. A., N. Mitlin and B. H. Nelson,Ibid 48, 9 (1955).
Mitlin, N.,Ibid 49, 683 (1956).
Mitchell, W., Pyrethrum Post5, 19 (1959).
Fales, J. H., O. F. Bodenheimer and M. Beroza, Soap Chem. Specialties33, 79 (1957).
Bruce, W. N., J. Econ. Entom.50, 828 (1957).
Gersdorff, W. A., P. G. Piquett, S. I. Gertler, and B. H. Alexander,Ibid 53, 282 (1960).
Fairchild, H. E., Chem. Specialties Mfrs. Assoc, Proc. Dec. 1957, p. 104; C. A.52, 14952i (1958).
Fairchild, H. E., Soap Chem. Specialties,34, 82,84,151 (1958) ; C. A. 52, 4918b (1958).
Fairchild. H. E., U.S. 2,948,654 (1960); C. A.54, 25544g (1960).
Fairchild, H. E., U.S. 2,920,993 (1960) ; C. A.54, 9196h (1960).
Sun, Yun-Pei, and E. R. Johnson, J. Econ. Entom.53, 887 (1960).
Moorefield, H. H., Contribs. Boyce Thompson Inst.19, 501 (1958). U.S. 2,904,465 (1959); C. A.54, 808a (1960).
Eldefrawi, M. E., E. Miskus and W. M. Hoskins, Science129, 898 (1959).
Eldefrawi, M. E., R. Miskus and V. Sutcher, J. Econ. Entom.53, 231 (1960).
Speirs, R. D.,Ibid 53, 974 (1960)
Clark, P. H., and M. M. Cole, U.S. Dept. Agr. ARS-33-62 (1960). C. A. 55, 21451f (1961).
Hartle, R. J., and H. I. Thayer, U.S. 2,951,850 (1960) ; C. A.55, 12756i (1961).
Hartle, R. J., and H. I. Thayer, U.S. 2,990,320 (1961) ; C. A.55, 22703b (1961).
Hartle, R. J., and H. I. Thayer, U.S. 3,035,969 (1962); C. A.57, 8966d (1962).
Metcalf, R. L., T. R. Fukuto and M. Y. Winton, J. Econ. Entomol.53, 828 (1960).
Hodgson, E., and J. E. Casida, Biochim. Biophys. Acta42, 184 (1960). Biochem. Pharmacol.8, 179 (1961).
Grunt, J. A., W. H. Knisely and R. J. Berry, Proc. Soc. Exptl. Biol. Med.94, 649 (1957).
Calhoon, T. B., and C. A. Angerer, Endocrinology46, 327 (1950).
Jasper, R. L., M. E. Denison, W. A. Hiestand and M. X. Zarrow, Proc. Soc. Exptl. Biol. Med.95, 417 (1957).
Denison, M. E., R. L. Jasper, W. A. Hiestand and M. X. Zarrow, Am. J. Physiol.186, 471 (1956).
Dicuattro, C., and T. Mercadante, Policlinico (Rome), Sez. Med.62, 171 (1955); C. A.49, 14172a (1955).
Mirand, E. A., M. C. Reinhard and H. L. Goltz, Exptl. Med. Surg.11, 286 (1953).
Anon., Am. Vet. Assoc. J.125, 464D (1954).
Bishoff, F., Fed. Proc.16, 155 (1957).
Bishoff. F., E. W. Sheller, G. Lopez and R. Fraundorf, J. Natl. Cancer Inst.19, 977 (1957).
Bishoff, F., J. J. Rupp, J. G. Turner, Jr., and G. Bryson, Proc. Am. Assoc. Cancer Res.2, 281 (1958).
Bishoff, F., Progr. exp. Tumor Res.3, 412 (1963).
Ambrose, A. M., A. J. Cox and F. DeEds, J. Agr. Food Chem.6, 600 (1958).
Gangadharam, P. R. J., S. Natarajan, T. K. Wadhwani, K. V. Giri, N. L. Narayanamurty and B. H. Iyer, J. Ind. Inst. Sci.35A, 69 (1953) ; C. A.47, 4413d (1953).
Ramaswamy, A. S., Naturwissenschaften44, 380 (1957) ; Chemotherapy, Proc. Symposium Lucknow 1958, p. 46; C. A.54, 4910g (1960).
Chou, T. C, and A. L. Marlatt, J. Nutr.51, 305 (1953).
Ershoff, B. H.,Ibid 71, 45 (1960).
Benton, C. H., and C. D., Robeson, U.S. 2,835,679 (1958) ; C. A.53, 2279c (1959).
Haroks, O. D., Brit. 778,753 (1957); C. A.52, 2077i (1958).
Naidu, M. B., and S. H. Zaheer, Indian 69,325 (Appl. 1959) ; C. A.56, 2519i (1962).
Moore, R. N., and W. G. Bickford, JAOCS29, 1 (1952).
Sahasrabudhe, M. R., J. Sci. Ind. Res. (India)12B, 63 (1953) ; C. A.47, 7238b (1953).
Oikawa, T., Kagaku to Sosa 9, 15 (1956) ; C. A.51, 8454h (1957).
Acharya, B. N., and B. G. Malpoorwala, J. Univ. Bombay, Sect. A,21, 53 (1952); C. A.47, 12548g (1953).
Roy, B. R., J. Indian Ohem. Soc, Ind. News Ed.15, 171 (1952); C. A.49, 2098i (1955).
Roy, B. R., Ann. Biochem. and Exp. Med. (India)12, 63 (1952) ; C. A.48, 4231 (1954) ; J. Indian Chem. Soc, Ind. News Ed.17, 90 (1954); C. A.49, 5863c (1955).
Sampath, S. R., C. P. Anantakrishnan and K. C. Sen, Indian J. Dairy Sci.10, 34 (1957); C. A.51, 18369f (1957).
Mathur, L. B., K. S. Tilara and R. Sahai, J. Indian Chem. Soc, Ind. News Ed.18, 123 (1955); C. A.50, 5309e (1956).
Dane, B. S., and B, S. Anantanarayanan, J. Sci. Ind. Research (India)170, 18 (1958); C. A.52, 12260b (1958).
Murray, M. D., R. T. O’Connor, O. C. Suarez and W. G. Biekford, JAOCS30, 329 (1953).
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Contribution from the National and University Institute of Agricul-ture, Rehovot, 1963, Series No. 566-E.