Abstract
The thermodynamic properties of silicon in liquid Ag-Si alloys in the range of 1100 to 1325°C have been measured by an electrochemical cell employing silica-saturated lithium silicate as the electrolyte. The range of composition studied is 0.015 <x Si < 0.29. For the change in standard state from pure liquid silicon to silicon at infinite dilution with the composition in atom fraction: Si(I) = Si (inf. dil.): △G° = 5,000 + 5.47T, (J/g-atom) The results of the study are in good agreement with the measurements on the phase diagram by Hager.
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Member of AIME; Visiting Scientist, Mass.(1969)
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Sakao, H., Elliott, J.F. thermodynamic properties of liquid Ag-Si alloys. Metall Trans 5, 2063–2067 (1974). https://doi.org/10.1007/BF02644499
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DOI: https://doi.org/10.1007/BF02644499