Abstract
The formation and properties of short-lived homo- and heteronuclear metal clusters in aqueous solutions were investigated by pulse radiolysis. These species arise in early stages of the aggregation of metal atoms and ions in unusual oxidation states. The conditions favoring the formation of positively charged “magic” clusters and intermediate heterometallic clusters were elucidated.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 1–15, January, 1999.
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Ershov, B.G. Short-lived metal clusters in aqueous solutions: formation, identification, and properties. Russ Chem Bull 48, 1–15 (1999). https://doi.org/10.1007/BF02494392
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DOI: https://doi.org/10.1007/BF02494392