Abstract
It is shown that using additive schemes complying with the general principle of structural analogy for all molecular transformations is admissible for calculating gas chromatographic retention indices, which are very important analytical parameters for identification of organic compounds. From this viewpoint, we compare the possibilities of using the homomorphism factors and the fit increments of the retention indices of reagents and products in chemical reactions, including those of some topochemically equivalent hypothetical transformations of the structure and composition of organic molecules.
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Scientific-Research Institute of Chemistry, St. Petersburg University. Translated fromZhurnal Strukturnoi Khimii, Vol. 37, No. 4, pp. 784–795, July–August, 1996.
Translated by L. Smolina
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Zenkevich, I.G. Structural analogy principle for estimating gas chromatographic retention indices. J Struct Chem 37, 674–682 (1996). https://doi.org/10.1007/BF02437183
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DOI: https://doi.org/10.1007/BF02437183