Abstract
The photolysis products of SO2-pentane-NO mixtures are N2O, H2O and a compound designated as RNO. Kinetic data obtained by OC method confirm the previously proposed scheme of photolysis. Also studied was the photolysis of SO2, NO and cyclohexane mixtures. From comparison of spectral characteristics of RNO and its analog 2-methyl-2-nitrosopropane, the probable structure of RNO is suggested.
Abstract
При фотолизе смесей SO2-пентан-NO зарегистрированы продукты N2O, H2O и смесь, обозначенная как RNO. Кинетические данные, полученные методом ГХ, подтвердили ранее предложенную схему фотолиза. Изучен также фотолиз смеси SO2 и NO с циклогексаном. Сопоставление спектральных характеристик RNO и предполагаемого аналога 2-метил-2-нитрозопропана позволило высказать предпожения о структуре RNO.
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Andreeva, T.A., Makarov, V.I., Skubnevskaya, G.I. et al. Photolysis of SO2-alkane-NO systems in the gas phase. React Kinet Catal Lett 19, 383–387 (1982). https://doi.org/10.1007/BF02074066
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DOI: https://doi.org/10.1007/BF02074066