Abstract
The kinetics of propane and isobutane oxidation by aqueous solutions of chromic acid in the presence of Ir(IV) chloride complexes has been studied. Reaction rate decreases with increasing Cl ion concentration and decreasing acidity. Ir(H2O)Cl −5 complexes are by an order of magnitude more active than IrCl 2−6 .
Abstract
Изучена кинетика окисления пропана и изобутана водными растворами хромовой кислоты в присутствии хлоридных хлоридных комплексов Ir(IV). Скорость реакции уменьшается с ростом концентрации Cl-ионов и понижением кислотности среды. Комплексы Ir(H2O)Cl −5 на порядок более активны, чем IrCl 2−6 .
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Arzamaskova, L.N., Romanenko, A.V. & Yermakov, Y.I. Kinetics of alkane oxidation by chromic acid in aqueous solutions of Ir(IV) chloride complexes. React Kinet Catal Lett 13, 395–400 (1980). https://doi.org/10.1007/BF02065706
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DOI: https://doi.org/10.1007/BF02065706