Abstract
Complexes of Co, Cu and Fe with bipyridyl, and cobalt complexes with ammonia, ethylenediamine and oxyacids are shown to be efficient catalysts for water oxidation by Ru(bpy) 3+3 in both alkaline and weakly acidic media. Partially hydrolyzed forms of these complexes are assumed to be active.
Abstract
Показано, что эффективными катализаторами реакции окисления воды комплексом Ru(bpy) 3+3 как в щелочной, так и в слабокислой среде явдяются дипиридильные соединения Co, Cu и Fe, а также комплексы кобальта с аммиаком, этилендиамином и оксикислотами. Предполагается, что активными являются частично гилролизованные формы этих комплексов.
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Elizarova, G.L., Matvienko, L.G., Lozhkina, N.V. et al. Homogeneous catalysts for dioxygen evolution from water. Water oxidation by trisbipyridylruthenium(III) in the presence of cobalt, iron and copper complexes. React Kinet Catal Lett 16, 191–194 (1981). https://doi.org/10.1007/BF02065456
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DOI: https://doi.org/10.1007/BF02065456