Abstract
The1HNMR method and chemical analysis indicate that a complex of Pt(IV) containing a CH3−Pt fragment is formed in the reaction of H2PtCl6+H2PtCl4 with methane at 120 °C in aqueous CF3CO2H. The complex was isolated from the solution as an adduct of Ph3P.
Abstract
Методом ПМР и химическим анализом показано, что при нагревании метана с растворм H2PtCl6 вприсутствии H2PtCl4 в водной CF3COOH при 120°C в течение двух часов образуется комплекс платины (IV), содержащий фрагмент Pt−CH3. Комплекс был выделен из раствора после добавления Ph3P в виде производного, включающего трифенилфосфин.
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Lavrushko, V.V., Lermontov, S.A. & Shilov, A.E. Formation of methyl platinum complex in the reaction of methane with chloroplatinic acid. React Kinet Catal Lett 15, 269–272 (1980). https://doi.org/10.1007/BF02062444
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DOI: https://doi.org/10.1007/BF02062444