Abstract
Cellulose has been pyrolysed in nitrogen at two heating rates, and the rates of formation of total gases, and the oxides of carbon, have been measured. The quantities of products formed, and their first order kinetic parameters, are strongly dependent on the heating rate.
Résumé
On a effectué la pyrolyse de la cellulose en atmosphère d'azote avec deux vitesses de chauffage et l'on a mesuré la vitesse de formation des gaz, dans leur totalité, ainsi que celle des oxydes de carbone. Les quantités de produits formés et leurs paramètres cinétiques du premier ordre dépendent fortement de la vitesse de chauffage.
Zusammenfassung
Cellulose wurde in Stickstoff-Atmosphäre bei zwei Aufheizungsgeschwindigkeiten pyrolysiert und die Bildungsgeschwindigkeiten der Gesamtgase sowie der Kohlenoxide gemessen. Die Mengen der gebildeten Produkte und ihre kinetischen Parameter erster Ordnung hängen stark von der Aufheizungsgeschwindigkeit ab.
Резюме
Был проведен пиролиз целлюлозы в атмосфер е азота при двух скорос тях нагрева. Скорость образовани я всех газов и окислов углерода была измерена. Количе ство образующихся продук тов и их кинетические параметры первого порядка знач ительно зависели от скорости нагрева.
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References
J. R. Welker, J. Fire and Flammability, 1 (1970) 12.
R. Alger, Natn. Bur. Stand. Special Publication, “The Mechanisms of Pyrolysis, Oxidation, and Burning of Organic Materials”, 357 (1972) 171.
W. K. Tang andW. K. Neill, J. Polym. Sci., C, 6 (1964) 65.
A. J. Stamm, Ind. Eng. Chem., 48 (1956) 413.
T. Hirata andH. Abe, Mokuzai Gakkaishi, 19 (1973) 451.
K. Akita andM. Kase, J. Polym. Sci., A, 5 (1967) 833.
D. Dollimore andB. Holt, J. Polym. Sci., A, 11 (1973) 1703.
K. S. Patel, K. C. Patel andR. D. Patel, Makromolek. Chem., 132 (1970) 7.
A. Basch andM. Lewin, J. Polym. Sci., A, 11 (1973) 3071.
R. J. McCarter, Textile Res. J., 42 (1972) 709.
E. J. Murphy, J. Polym. Sci., 58 (1962) 649.
D. J. Bryce andC. T. Greenwood, “Thermal Analysis of Fibres and Fibre-Forming Polymers”, Edited by R. F. Schwenker Jr., Interscience, New York, 1966, p. 149.
A. Murty Kanury, Combust. Flame, 18 (1972) 75.
A. E. Lipska andF. A. Wodley, J. Appl. Polym. Sci., 13 (1969) 851.
S. L. Madovsky, V. E. Hart andS. Straus, J. Res. Natl. Bur. Stand., 56 (1956) 343.
D. P. C. Fung, Tappi, 52 (1969) 319.
H. Okamoto, Mokuzai Gakkaishi, 19 (1973) 353.
Y. Tsuchiya andK. Sumi, J. Appl. Polym. Sci., 14 (1970) 2003.
F. A. Wodley, J. Appl. Polym. Sci., 15 (1971) 835.
F. Shafizadeh, Adv. Carbohyd. Chem., 23 (1968) 419.
R. R. Baker andK. D. Kilburn, Beitr. Tabakforsch., 7 (1973) 79.
R. R. Baker, Beitr. Tabakforsch., 8 (1975) 16.
P. H. S. Henry, Proc. Roy. Soc., A, 171 (1939) 215.
M. M. Tang andR. Bacon, Carbon, 2 (1964) 211.
E. W. Stern, A. S. Logiudice andH. Heinemann, Ind. Eng. Chem., Process Des. and Dev., 4 (1965) 171.
J. J. Kipling, Q. Rev. Chem. Soc., 10 (1956) 1.
E. L. Back, M. T. Htun, M. Jackson andF. Johanson, Tappi, 50 (1967) 542.
D. Dollimore andG. R. Heal, Carbon, 5 (1967) 65.
R. F. Schwenker Jr. andL. R. Beck Jr., J. Polym. Sci., C, 2 (1963) 331.
P. K. Chatterjee andC. M. Conrad, Textile Res. J., 36 (1966) 487.
A. E. Lipska andW. J. Parker, J. Appl. Polym. Sci., 10 (1966) 1439.
U. K. Shivadev andH. W. Emmons, Combust. Flame, 22 (1974) 223.
M. V. Ramiah, J. Appl. Polym. Sci., 14 (1970) 1323.
A. F. Roberts, J. Appl. Polym. Sci., 14 (1970) 244.
M. V. Ramiah andD. A. L. Goring, Cell. Chem. Technol., 1 (1967) 277.
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Baker, R.R. Thermal decomposition of cellulose. Journal of Thermal Analysis 8, 163–173 (1975). https://doi.org/10.1007/BF01912473
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DOI: https://doi.org/10.1007/BF01912473