Summary
Solid tetraphenylboronates of some cations,e.g. [Fe(1,10 phen)3]3+ , [Co(NH3)6]3+, with E° values ⩾-0.26V are unstable, either thermally or photo chemically, or both. Products of such redox reactions are identified. The contrasting situation with more reducing cations,e.g. [Cr(en)3 ]3+, is described.
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On leave from Paisley College of Technology, Renfrewshire, Scotland, U.K.
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Gillard, R.D., Vaughan, D.H. Properties of some tetraphenylboronates of transition metal complexes. Transition Met Chem 3, 44–48 (1978). https://doi.org/10.1007/BF01393504
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DOI: https://doi.org/10.1007/BF01393504