Abstract
Fluorescence enhancement of 8-hydroxyquinoline-5-sulfonic acid complexes of Mg, Ca, Sr, Ba, Al, Zn and Cd were studied in micellar and hydroorganic solvents. Al is extraordinarily amenable to both types of fluorescence enhancement, an order of magnitude to two order of magnitude enhancement of fluorescence intensity has been observed with aqueous hexadecyltrimethylammonium chloride (HTAC) and certain mixed aqueous-organic solvents. Fe(III) appears to be an unusually powerful fluorescence quencher in these systems — the effect is noticeable in low micromolar concentrations and is greatly amplified by cationic surfactants such as HTAC.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
R. G. W. Hollingshead,Oxine and Its Derivatives, Vol. I–IV, Butterworths, London, 1954–1956.
M. P. Bratzel, J. J. Aaron, J. D. Winefordner, S. G. Schulman, H. Gershon,Anal. Chem. 1972,44, 1240.
O. Popovych, L. B. Rogers,Spectrochim. Acta 1959,15, 584.
R. E. Ballard, J. W. Edwards,J. Chem. Soc. 1964, 4868.
S. G. Schulman, Q. Fernando,Tetrahedron 1968,24, 1777.
A. Fernandez-Gutierrez, A. Munoz de La Pena, in:Molecular Luminescence Spectroscopy, Methods and Applications, Part I (S. G. Schulman, ed.), Wiley, New York, 1985.
G. F. Kirkbright, in:Indicators (E. Bishop, ed.), Pergamon, Oxford, 1972.
R. S. Becker,Theory and Interpretation of Fluorescence and Phosphorescence, Wiley, New York, 1972.
C. E. White, R. J. Argauer,Fluorescence Analysis: A Practical Approach, Marcel Dekker, New York, 1970.
W. R. Seitz,Crit. Rev. Anal. Chem. 1980,8, 367.
R. D. Haugland,Molecular Probes: Handbook of Fluorescent Probes, Molecular Probes, Junction City, 1985.
R. M. Cassidy, B. D. Karchner, in:Reaction Detection in Liquid Chromatography (I. S. Krull, ed.), Marcel Dekker, New York, 1986, p. 129.
J. W. McLaren, A. P. Myktiuk, S. N. Willie, S. S. Berman,Anal. Chem. 1985,57, 2907.
K. Soroka, R. S. Vithange, D. A. Phillips, B. Walker, P. K. Dasgupta,Anal. Chem. 1987,59, 629.
W. L. Hinze, H. N. Singh, Y. Baba, N. G. Harvey,Trends Anal. Chem. 1984,3, 193.
S. B. Meshkova, N. B. Rusakova, N. S. Pouletkov,Zh. Analit. Khim. 1982,37, 1988.
C. A. Bunton,Progr. Solid State Chem. 1979,8, 329.
J. B. S. Bonilha, G. Chiericato, Jr., S. M. Martin-Franchetti, E. J. Ribaldo, F. H. Quina,J. Phys. Chem. 1982,86, 4941.
W. L. Hinze, T. E. Riehl, H. N. Singh, Y. Baba,Anal. Chem. 1984,56, 2180.
Y. Kondoh, M. Kataoka, T. Kambara,Bunseki Kagaku 1981,30, 109.
Y. Kondoh, M. Kataoka, T. Kambara,Bull. Chem. Soc. Jap. 1982,55, 434.
K. Kina, K. Tamura, N. Ishibashi,Bunseki Kagaku 1974,23, 1404.
H. Shi, W. Cui, R. Wang,Gaodeng Xuexiao Huaxue Xuebao 1982, 46.
H. Shi, W. Cui, R. Wang,Huaxue Xuebao 1983,41, 1029.
W. Cui, H. Shi,Fenxi Huaxue 1983,11, 778.
W. Cui, J. Wang, H. Shi,Fenxi Huaxue 1983,11, 900.
W. Cui, L. Mi, W. Shi,Huaxue Shiji 1985,7, 125.
C. A. Bunton, L. S. Romsted, L. Sepulveda,J. Phys. Chem. 1980,84, 2611.
L. S. Romsted, in:Surfactants in Solution (K. L. Mittal, B. Lindman, eds.), Plenum, New York, 1984.
L. S. Romsted,J. Phys. Chem. 1985,89, 5107.
O. Popovych, L. B. Rogers,Spectrochim. Acta 1960,16, 49.
Z. Zhujun, W. R. Seitz,Anal. Chim. Acta 1985,171, 125.
P. K. Dasgupta, in:Ion Chromatography (J. G. Tarter, ed.), Marcel Dekker, New York, 1986.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Phillips, D.A., Soroka, K., Vithanage, R.S. et al. Enhancement and quenching of fluorescence of metal chelates of 8-hydroxyquinoline-5-sulfonic acid. Mikrochim Acta 88, 207–220 (1986). https://doi.org/10.1007/BF01196613
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01196613