Abstract
A theoretical and experimental investigation is made of the electron-beam-controlled method of synthesizing nitrogen-containing compounds. It is shown that the basic chemically active form of nitrogen in the electron-beam-controlled discharge are the vibrationally excited molecules N2. The experimental procedure and the results are meported on the synthesis of nitrogen oxides, hydrogen cyanide, and phosphorus nitride. The isotopic compositions of the vibrationally excited nitrogen and carbon monoxide are calculated.
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Literature Cited
F. K. MacTaggart, Plasma Chemistry in Electrical Discharges, Am. Elsevier, New York (1967).
S. Ya. Pschezhetskii, Mechanism of Radiation-Chemistry Reactions [in Russian], Khimiya, (1968).
N. G. Basov et al., Electroinization Stimulation of Chemical Reactions [in Russian], FIAN Report, Moscow (1975).
A. N. Lobanov and A. F. Suchkov, Kvantovaya Elektron. (Moscow),1, 1527 (1974).
R. B. Cohen, Chem. Phys. Lett.,30, 284 (1975).
A. L. Schmeltekopf, E. E. Ferguson, F. S. Fehsenfeld, J. Chem. Phys.,48, 2966 (1968).
S. E. Jaffe and J. B. Anderson, J. Chem. Phys.,51, 1057 (1969).
N. G. Basov, É. M. Belenov, E. P. Markin, A. N. Oraevskii, and A. V. Pankratov, Zh. Eksp. Teor. Fiz.,64, 485 (1973).
N. G. Basov, V. A. Danilychev, V. I. Panteleev, V. I. Popovichev, V. V. Ragul'skii, A. V. Suchkov, F. S. Faizullov, Yu. N. Shebeko, A. M. Alekseev, É. V. Gorozhankin, V. V. Kurenkov, and V. T. Pendrakovskii, Dokl. Akad. Nauk SSSR,233, 839 (1977).
N. G. Basov, V. A. Danilychev, V. I. Panteleev, V. I. Popovichev, V. V. Ragul'skii, A. F. Suchkov, F. S. Faizullov, and Yu. N. Shebeko, Khim. Vys. Energ.,12, 3 (1978).
É. V. Gorzhankin, V. V. Kurenkov, and V. I. Panteleev, “Electroionization synthesis of phosphorus nitrides,” Abstracts of Second All-Union Conference on Plasma-Chemistry Technology, Moscow (1977), p. 43.
N. G. Basov, É. M. Belenov, V. A. Isakov, E. P. Markin, A. N. Oraevskii, V. I. Romanenko, and N. B. Ferapontov, Zh. Eksp. Teor. Fiz.,68, 2032 (1975).
T. J. Manuccia and M. D. Clark, Appl. Phys. Lett.,28, 372 (1976).
É. M. Belenov, V. A. Isakov, E. P. Markov, and V. I. Romanenko, Kratkie Soobshch. Fiz., No. 6, 17 (1976).
N. N. Sobolev and V. V. Sokovikov, Usp. Fiz. Nauk,110, 191 (1973).
C. T. Hsu and L. D. McMillen, J. Chem. Phys.,56, 5327 (1972).
L. S. Polak, P. A. Sergeev, and D. I. Slovetskii, Khim. Vys. Energ.,7, 387 (1973).
V. A. Kuz'min, L. S. Polak, P. A. Sergeev, D. I. Slovetskii, Khim. Vys. Energ.,8, 129 (1974).
V. A. Kuz'min, L. S. Polak, P. A. Sergeev, and D. I. Slovetskii, Preprint of Paper at Interinstitute Seminar on Generalized Chemical Kinetics, Inst. New Chem. Prob., USSR Acad. Sci. (1974).
L. S. Polak, P. A. Sergeev, and D. I. Slovetskii, in: Experimental and Theoretical Investigation of Nonequilibrium Physicochemical Processes, Inst. Inorg. Chem. Comp., USSR Acad. Sci., Moscow (1974), Part 3, pp. 392.
N. G. Basov, V. I. Dolinina, A. F. Suchkov, and B. M. Urin, Preprint No. 1, FIAN, Moscow (1976).
S. D. Rockwood, J. E. Brau, W. A. Proctor, and G. H. Canarvan, IEEE J. Quantum Electron.,QE-9, 120 (1973).
K. N. C. Bray, J. Phys. B.,1, 705 (1968).
R. E. Center and G. A. Caledonia, Appl. Opt.,10, 1795 (1971).
J. C. Y. Chen, J. Chem. Phys.,40, 3513 (1964)
B. F. Gordiets, Sh. S. Mamedov, and L. A. Shelepin, Zh. Eksp. Teor. Fiz.,67, 1287 (1974).
A. Chutjian and G. A. Segal, J. Chem. Phys.,57, 3069 (1972).
G. E. Zahr, R. K. Preston, and W. H. Miller, J. Chem. Phys.,62, 1127 (1975).
M. Karplus, R. N. Porter, and R. D. Sharma, J. Chem. Phys.,43, 3259 (1965).
D. Bunker in: Computational Methods in Physics of Atomic and Molecular Collisions [Russian translation], Mir, Moscow (1974), p. 277.
P. L. Wilkins, J. Chem. Phys.,58, 3038 (1973).
E. R. Fisher and E. Bauer, J. Chem. Phys., 59, 1966 (1973).
N. C. Blais and D. L. Bunker, J. Chem. Phys.,37, 2713 (1962).
G. Herzberg, Molecular Spectra and Molecular Structure, Vol. 2, Infrared and Raman Spectra of Polyatomic Molecules, Van Nostrand, New York (1945).
É. M. Belenov, E. P. Markin, A. N. Oraevskii, and V. I. Romanenko, Pis'ma Zh. Eksp. Teor. Fiz.,18, 196 (1973).
A. N. Oraevskii, N. B. Rodionov, A. A. Stepanov, and V. A. Shcheglov, Khim. Vys. Energ.,11, 269 (1977).
N. G. Basov, V. I. Dolinina, A. F. Suchkov, and B. M. Urin, FIAN Preprint No. 9, Moscow (1977).
C. E. Treanor, J. W. Rich, and R. G. Rekm, J. Chem. Phys.,48, 1798 (1968).
V. I. Dolinina, A. N. Oraevskii, A. F. Suchkov, B. M. Urin, and Yu. N. Shebeko, Zh. Tekh. Fiz.,48 (1978).
A. N. Oraevskii, A. F. Suchkov, and Yu. N. Shebeko, Khim. Vys. Energ.,12, (1978).
H. G. Basov, V. A. Danilychev, A. N. Lobanov, A. N. Oraevskii, V. I. Panteleev, V. I. Popovichev, V. V. Ragul'skii, A. F. Suchkov, B. M. Urin, F. S. Faizullov, Yu. N. Shebeko, É. V. Gorozhanin, and V. V. Kurenkov, FIAN Preprint, Moscow (1978).
A. N. Lobanov, A. F. Suchkov, and Yu. N. Shebeko, Khim. Vys. Energ.,11, 395 (1977).
W. L. Vighan, Phys. Rev. A,2, 1989 (1970).
N. G. Basov et al., Kvantovaya Elektron. (Moscow),3, 121 (1971).
N. G. Basov et al., Usp. Fiz. Nauk,114 213 (1974).
I. B. Kovsh, Candidate's Dissertation, FIAN, Moscow (1975).
N. G. Basov, É. M. Belenov, et al., Zh. Eksp. Teor. Fiz.,64, 109 (1973).
E. W. McDaniel, Collision Phenomena in Ionized Gases, Wiley, New York (1964).
R. Pages, D. L., Bertel, K. N. Joffre, and J. J. Sklavents, Vol. 4, No. 1, Atomic Data (1972).
E. A. Abramyan and S. B. Vasserman, At. Energ.,23, 165 (1967).
Yu. G. Bamburov, S. V., Vasserman, V. M., Doltushin, V. F. Kutsenko, N. G. Khavin, and B. I. Yastreba, At. Energ.,40, 308 (1976).
T. LaCapelle and H. B. Heller, Trans. AIME,230, No. 2, 311–314 (1964).
Report of Dnepropetrovsk State University, No. 75018673, Dneptropetrovsk (1976).
J. R. van Wazer, Phosphorus and Its Compounds, Interscience (1958, 1961).
A. Stock and H. Grunenberg, Chem. Ber.,40, 2573 (1907).
H. Mouren and P. Bocquet, Bull. Soc. Chim. France,3, 1801 (1936).
H. Mouren and E. Wetreff, C. R. Acad. Sci.,207, 915 (1934).
E. Huffmon, D. Tarbutton, K. C. Elmore, W. E. Cate, H. K. Walters, and E. V. Elmor, J. Am. Chem. Soc.,76, 6239 (1954).
H. Mouren and H. Fiegnelment, C. R. Acad. Sci.,198, 1417 (1934).
V. F. Plotnikov and M. L. Kuz'min, Zh. Prikl. Khim.,8, 429 (1935).
E. S. Deshmuck and J. D. Kahl, Proc. Soc. Ind. Acad. Sci.,25A, 247 (1947).
A. H. Gerzog and M. L. Nielsen, Ann. Chem.,30, 1490 (1958).
E. O. Huffman, E. Tarbutton, E. V. Elmore, A. J. Smith, and M. E. Rauntree, J. Am. Chem. Soc.,79, 1765 (1957).
E. Clementi, Chem. Ber.,87, 333 (1954).
I. P. Ubellya and T. N. Miller, Izv. Akad. Nauk Lat. SSR, Ser. Khim., 540 (1973).
A. A. Baltkaula, T. N. Miller, A. P. Puzinya, G. V. Ozolinysh, and A. Ya. Vaivad, Izv. Akad. Nauk Lat. SSR, Ser. Khim., 761 (1968).
A. A. Baltkaula, T. N. Miller, A. P. Puzinya, G. V. Ozolinysh, and A. Ya. Vaivad, Izv. Akad. Nauk Lat. SSR, Ser. Khim., 750 (1967).
E. Stegger, Chem. Ber.,4, 266 (1961).
A. A. Baltkaula and T. N. Miller, Izv. Akad. Nauk Lat. SSR, Ser. Khim., 389 (1971).
A. P. Mel'nik, Yu. A. Mel'nikov, et al., Second Symp. on Plasmochemistry, Abstracts of Papers Riga (1975).
P. G. Hendra, R. A. Johns, C. T. S. Miles, G. J. Vear, and A. B. Burg, Spectrochim. Acta,26A, 2169 (1970).
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Translated from Trudy Ordena Lenina Fizicheskogo Institute im. P. N. Lebedeva, Vol. 116, pp. 146–180, 1980.
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Basov, N.G., Danilychev, V.A., Dolinina, V.I. et al. Theoretical and experimental investigation of electron-beam-controlled synthesis of nitrogen-containing compounds. J Russ Laser Res 2, 26–56 (1981). https://doi.org/10.1007/BF01120840
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DOI: https://doi.org/10.1007/BF01120840