Abstract
Experimental data on the investigation of the water-trimethyleneoxide system,P, t, x phase diagram (up to 6 kbar) are presented. The results are compared with those on water systems with ethyleneoxide, 1,3- and 1,4-dioxane, 1,3-dioxolane and tetrahydrofuran, on the basis of which a summarizedP, t, x diagram is plotted for water-cyclic ether systems. It is shown that in all the systems in which a cubic structure II hydrate forms at 1 bar, it eventually turns to cubic structure I under pressure. The nature of high pressure hydrates is discussed.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
D. F. Sargent and L. D. Calvert:J. Phys. Chem. 70, 2689 (1966).
R. E. Hawkins and D. W. Davidson:J. Phys. Chem. 70, 1889 (1966).
L. Carbonnel and J. -C. Rosso:Rev Chem. Miner. 9, 771 (1972).
S. R. Gough, S. K. Garg, and D. W. Davidson:J. Chem. Phys. 3, 239 (1974).
O Maass and E. H. Broomer:J. Am. Chem. Soc. 44, 1709 (1922).
H. A. Palmer:Proc. Okla. Acad. Sci. 30, 1400 (1949), cit. from. [7].
J. Erva:Suomen Kemist. 10, 29B, 183 (1956).
B. D. Thorpe and K. L. Pinder:Suomen Kemist. 38, 243 (1965).
R. K. McMullan and G. A. Jeffrey:J. Chem. Phys. 42, 2725 (1965).
T. C. W. Mak and R. K. McMullan:J. Chem. Phys. 42, 2732 (1965).
S. R. Gough and D. W. Davidson:Can. J. Chem. 49, 2691 (1971).
M. Stackelberg:Naturwiss,36, 327 (1949).
M. Stackleberg and B. Meuthen:Z. Electrochem. 62, 130 (1958).
Yu. A. Dyadin, P. N. Kuznetsov, I. I. Yakovlev, and A. V. Pyrinova:Dokl. Akad. Nauk SSSR 208, 103 (1973);C.A. 78, 102558r (l973);Izv. Sib. Old. Akad. Nauk. SSSR. Ser. khim. nauk,4, 3 (1972)C.A. 77, 1566070d (1972).
Yu. A. Dyadin, P. N. Kuznetsov, and I. I. Yakovlev:Izv. Sib. Old. Akad. Nauk SSSR. Ser. khim. nauk. 2, 30 (1976).C.A. 84, 156307a (1976).
Yu. M. Zelenin, Yu. A. Dyadin, and F. V. Zhurko:VINITI, N 5239 Dep. (1984).
Yu. A. Dyadin, I. V. Bondaryuk, G. L. Rijikova, Ye. Ya. Aladko, and Yu. M. Zelenin:Izv. Sib. Old. Akad. Nauk SSSR. Ser. khim. nauk. 8, 67 (1984).C.A. 101, 64836p (1984).
Yu. A. Dyadin, P. N. Kuznetsov, and I. I. Yakovlev.Izv. Sib. Old. Akad. Nauk. SSSR, Ser. khim. nauk. 7, (1975).C.A. 83, 183514b (1975).
B. Bartok:Acta. Univ. Szeged, Acta Phys. Chem. 8, 133 (1962).
D. S. Tsiklis: Tekhnika ftziko-khimicheskikh issledovanii pri visokikh i sverkhvisokikh davelniyakh. M. Khimia (1976).
V. S. Bogdanov and A. P. Miroshnikov:Trudi metrologicheskikh institutov SSSR. M;104, 33 (1969).
J. -C. Rosso and L. Carbonnel:C.R. Acad. Sci. Paris 274, 1108 (1972).
A. I. Kitaygorodskii:Smeshanyi Kristally. Nauka, 276 (1983).
Yu. A. Dyadin and K. A. Udachin:J. Incl. Phenom. 2, 61 (1984).
D. W. Davidson: ‘Clathrate Hydrates’. Ch. 3 in Water. A Comprehensive Treatise, vol. 2, N.-Y, London, p. 115 (1973).
D. W. Davidson, S. K. Garg, and Y. P. Handa:J. Incl. Phenom. 2, 231 (1984).
D. W. Davidson. Y. P. Handa, C. J. Ratcliffe, and J. A. Ripmeester:Mol. Cryst. Liq. Cryst. 141, 141 (1986).
D. W. Davidson and Y. P. Handa:Nature 311, 5982, 142 (1984).
R. G. Ross and P. Andersson:Can. J. Chem. 60, 881 (1982).
R. G. Ross and P. Andersson:Nature 290, 5804, 322 (1981).
I. I. Novikov:Dokl. Akad. Nauk SSSR. 100, 1119 (1955).
D. N. Glew and N. S. Rath:J. Chem. Phys. 44, 1710 (1966).
R. K. McMullan and G. A. Jeffrey:J. Chem. Phys. 42, 2725 (1965).
J. E. Bertie and S. M. Jacobs:J. Chem. Phys. 69, 4105 (1978).
K. W. Morcom and R. W. Smith:J. Chem. Thermodyn. 3, 507 (1971).
D. W. Davidson, S. R. Gough, F. Lee, and J. A. Ripmeester:Rev. Chim. Miner. 447, 14 (1977).
H. Nakayama and M. Tahara:Bull. Chem. Soc. Jpn. 46, 2965 (1973).
S. R. Gough, J. A. Ripmeester, and D. W. Davidson:Can. J. Chem. 53, 2215 (1975).
L. V. Vilkov, V. S. Mastryukov, and N. 1. Sadova:Opredelenie geometricheskogo stroeniya svobodnikh molekul. M., Khimia (1978).
Yu. V. Zefirov and P. M. Zorkii:Zh. Struct. Khim. 15, 118 (1974).
W. F. Claussen:J. Chem. Phys. 19, 259 (l951).
M. Stackelberg:J. Chem. Phys. 19, 1319 (1951).
M. Stackelberg:Angew. Chem. 64, 423 (l452).
L. Pauling and R. E. Marsh:Proc. Acad. Sci. 38, 112 (1952).
K. W. Allen and G. A. Jeffrey:J. Chem. Phys. 38, 2304 (1963).
S. L. Miller, S. R. Gough, and D. W. Davidson:J. Phys. Chem. 81, 2154 (l977).
Yu. A. Dyadin and L. S. Aladko:Zh. Strukt. Khim. 18, 51 (1977).C.A. 87, 12297m (1977).
D. R. Hafemann and S. L. Miller:J. Phys. Chem. 73, 1392 (1969).
S. L. Miller and W. D. Smythe:Science 170, 533 (1970).
F. V. Zhurko, G. G. Zhurko, and Yu. A. Dyadin:Izv. Sib. Old. Akad. Nauk SSSR. Ser. khim. nauk. 5, 72 (1989).
Y. P. Handa, R. E. Hawkins, and J. J. Murray:J. Chem. Thermodyn. 16, 623 (l984).
Y. P. Handa:J. Chem. Thermodyn. 17, 201 (l985).
Y. P. Handa:Can. J. Chem. 63, 68 (1985).
Y. P. Handa C. 1. Ratcliffe, J. A. Ripmeester, and J. S. Tse:Abstracts of Gas Hydrate Symposium, Toronto, June 1988.
D. W. Davidson, S. R. Gough, F. Lee, and J. A. Ripmeester:Rev. Chem. Min. 14, 447 (l977).
J. E. Bertie and S. M. Jacobs:Can. J. Chem. 55, 1777 (1977).
J. A. Ripmeester, J. S. Tse, J. R. Christopher, and B. M. Powell:Nature 325, 135 (l986).
Author information
Authors and Affiliations
Additional information
Dedicated to the memory of D. W. Davidson.
Rights and permissions
About this article
Cite this article
Dyadin, Y.A., Zhurko, F.V., Bondaryuk, I.V. et al. Clathrate formation in water-cyclic ether systems at high pressures. J Incl Phenom Macrocycl Chem 10, 39–56 (1991). https://doi.org/10.1007/BF01041638
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF01041638