Abstract
Using a photodissociation technique, we have measured the IR spectrum of thev 21 mode of the (CF3)3 CI molecule with a vibrational energy ofE 2=42500±3500 cm−1 which is more than two times the dissociation energy. The experimental spectrum of a Lorenzian shape with a halfwidth of γ2=10.8±1.5 cm-1 has been analyzed simultaneously with the results of the preceding work (γ1=8.6±0.6 cm-1) that were obtained at a lower vibrational energy (E 1=36500±2500 cm−1).
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Ionov, S.I., Stuchebryukhov, A.A., Bagratashvili, V.N. et al. Evolution of the homogeneous IR spectrum of a highly vibrationally excited molecule as a result of a change in its vibrational energy. Appl. Phys. B 47, 229–232 (1988). https://doi.org/10.1007/BF00697341
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DOI: https://doi.org/10.1007/BF00697341