Abstract
This paper reviews the various physico-chemical processes responsible for actual linewidths encountered in high-resolution coherent anti-Stokes Raman spectroscopy (CARS). Most of the experimental data are based on linewidth measurements using a pulseamplified CARS spectrometer with an emission bandwidth (FWHM) of 2×10−3 cm−1. Detailed rotational and vibrational relaxation constants have been obtained from the analysis of theQ-branch profiles of C2H2, N2, CH4, and SiH4.
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Kozlov, D.N., Smirnov, V.V. & Volkov, S.Y. Study of processes of translational, rotational, and vibrational relaxation based on CARS spectra line shapes. Appl. Phys. B 48, 273–283 (1989). https://doi.org/10.1007/BF00694359
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DOI: https://doi.org/10.1007/BF00694359