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Abbreviations
- C o :
-
bulk concentration
- C s :
-
surface concentration
- C tip :
-
concentration at the top of growing protrusion
- D :
-
diffusion coefficient
- F :
-
Faraday constant
- f :
-
exp (η/η0, c) — exp (−η/η0,a)
- f 1 :
-
exp (η/η0,c)
- f 2 :
-
exp (−η/η0,a)
- h :
-
the height of growing protrusion
- h 0 :
-
initial height of protrusion
- i :
-
current density
- i 0 :
-
exchange current density
- i L :
-
limiting current density
- i tip :
-
current density at the tip of growing protrusion
- k 1 :
-
constant
- k 2 :
-
constant
- n :
-
number of electrons
- N :
-
number of nuclei
- N 0 :
-
maximum number of nuclei
- r :
-
radius of growing nucleus
- r c :
-
radius of growing nucleus at which deposition becomes mixed controlled
- t :
-
time
- t i :
-
induction time for spongy growth initiation
- t i,h :
-
induction time for the formation of diffusion layer
- V :
-
molar volume
- δ :
-
thickness of diffusion layer
- η :
-
overpotential
- 2.3η0,c :
-
slope cathodic Tafel line
References
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Idem, ibid. 13 (1983) 765.
K. I. Popov and N. V. Krstajić,ibid. 13 (1983) 775.
M. Fleischman and H. R. Thirsk,Electrochim. Acta 1 (1959) 146.
A. R. Despić and K. I. Popov,Mod. Aspects Electrochem. 7 (1972) 199.
K. I. Popov, M. D. Maksimović, J. D. Tmjančev and M. G. Pavlović,J. Appl. Electrochem. 11 (1981) 239.
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Popov, K.I., Krstajić, N.V. & Popov, S.R. The morphology of cadmium deposits obtained on foreign substrates at high overpotentials. J Appl Electrochem 15, 151–154 (1985). https://doi.org/10.1007/BF00617753
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DOI: https://doi.org/10.1007/BF00617753