Summary
Inorganic anions as well as carboxylic acids in eluates of stone can be separated by anion-exchange chromatography using a gradient elution system. This separation required a HPIC-AS5A(5 μ) (DIONEX) separator column, anion micro membrane suppressor (AMMS) (DIONEX) and a continous NaOH-gradient. The gradient started with an initial concentration of 0.75 mmol/l NaOH, 203 mmol/l NaOH was added. An “Anion Trap Column” (4×50 mm) between injector and pump served to clean the NaOH-eluents. Reproducibility and linearity of the gradient method were satisfactory.
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Literatur
Blaschke R (1986) Sonderheft 38, Bautenschutz Bausanierung. Verlagsgesellschaft Rudolf Müller GmbH, Köln
Wolters B, Sand W, Ahlers B, Sameluck D, Meincke C, Krause-Kupsch T, Bock E (1988) VIth International Congress on Determination and Conversation of Stone, Torufi
Eckhardt FEW (1982) Habilitationsschrift „Mikroorganismen und Gesteinsverwitterung“. Math Naturwiss Fak, Universität Kiel
Weiß J (1985) Handbuch der Ionenchromatographie. VCH GmbH Weinheim
Hansen LB, Richter BE, Rollins DK, Lambs JD, Eatough DJ (1979) Anal Chem 51:633
Trujillo FJ, Miller MM, Skoherboe RK, Taylor HE, Grant CL (1981) Anal Chem 53:1944
DIONEX Application Note 7R (1982) DIONEX: Sunny vale, CA
Rocklin RD, Johnson EL (1983) Anal Chem 55:4
Pimminger M, Puxbaum H, Kossina J, Weber M (1985) Fresenius Z Anal Chem. 320:445
Schwikowski M (1986) Diplomarbeit „Untersuchungen zur Simultanbestimmung von Anionen in Regenwasser unter Anwendung der lonenchromatographie“. Fachber Chem, Universität Hamburg
Rocklin RD, Pohl CA, Schibier JA (1987) J Chromatogr 411:107
Sunden T, Cedergren A (1984) Anal Chem 56:1085
Siemer DD, Johnson VJ (1984) Anal Chem 56:1033
Selke K (1988) Diplomarbeit „Einsatz eines Gradientensystems zur ionenchromatographischen Bestimmung von Anionen in ausgewählten Proben“. Fachber Chem, Universität Hamburg
Shintani H, Dasgupta PK (1987) Anal Chem 59:802
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Dannecker, W., Selke, K. Simultanbestimmung organischer und anorganischer Anionen aus verwitterten Natursteinoberflächen mittels Gradienten-Ionen-Chromatographie. Z. Anal. Chem. 335, 966–970 (1989). https://doi.org/10.1007/BF00466390
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DOI: https://doi.org/10.1007/BF00466390