Abstract
Total Hg and McHg concentrations have been determined in sediments and suspended particulate matter from one of the most Hg-polluted rivers of the world, the Elbe river in Northern Germany. Results of total Hg and McHg are presented. Total Hg concentrations in suspended particulate matter (SPM) are 30 mg kg−1 in the average and up to 150 mg kg−1 as the maximum value. Total Hg-fluxes −1 calculated from measurements of an automatically operating station upstream Hamburg as about 17 ta−1 in suspended particles. A new McHg determination by HPLC chromatography and photometric detection was developed and verified. Methylmercury concentrations were up to 10% of the total Hg, i. e. 2.7 mg kg−1 (dw).
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References
Arbeitsgemeinschaft für die Reinhaltung der Elbe: 1988, Schwermetalldaten der Elbe von Schnackenburg bis zur See, 1984–1988.
Banat, K., Förstner, U. and Müller, G.: 1972, Die Naturwissenschaften. 59, 525.
Bartholome, E., Biekert, E., Hellmann, H., and Ullmann (ed.): 1980, ‘Encyclopedia of technical chemistry’, 19, 4th edition, 644–671.
Bartlett, P. P., Craig, P. J. and Morton, S. F.: 1978, Sci. Total Environ. 10, 245.
Callister, S. M. and Winfrey, M. R.: 1986, Water Air Soil Poll. 29, 453.
Cappon, C. J. and Smith, J. C.: 1977, Anal. Chem. 49, 385.
Evans, O. and McKee, G. D.: 1988, Analyst 113, 243.
Frimmel, F. and Winkler, H. A.: 1975a, Z. Wasser Abwasser. 8, 67.
Greiser, N.: 1988. Hamburger Küstenforschung 45, 1.
Hatch, W. R. and Ott, W. L.: 1968, Anal. Chem.. 40, 2085.
Kodu, A., Agaki, H., Mortimer, D. C. and Miller, D. R.: 1977, Nature 270, 419.
Krull, E.S., Bushee, D. S., Schleicher, R. G. and Smith, S. B.: 1986, Analyst 11, 245.
MacCrehan, W. A., Durst, R. A. and Bellama, G. M.: 1977, Anal. Letters 10, 1175.
Merian, E.: 1984, Metalle in der Umwelt: Verteilung, Analytik und biologische Relevanz; Verlag Chemie GmbH, Weinheim.
Robertson, D. E., Sclarew, D. S., Olson, K. B., Bloom, N. S., Crecelius, E. A. and Apts, C. W.: 1987, ‘Measurement of bioavailable mercury species in fresh water and sediments’ Research Project 2020-3, Final report, Batelle Pacific Northwest Laboratories.
Robinson, J. B. and Tuovinen, O. H.: 1984, Microbiol. reviews 48, 95.
Schucknecht, T. and König, K.- H.: 1988, Fresenius Z. Anal. Chem.. 332, 62.
Thayer, J. S.: 1989, Appl. Organo. Chem. 3, 123.
Umweltbundesamt (Ed): 1989, Daten zur Umwelt. Erich Schmidt Verlag, Berlin, 382.
Wilken, R.-D., Hintelmann, H. and Ebinghaus, R.: 1990, Vom Wasser 74, 383.
Wilken, R.-D. and Hintelmann, H.: 1990, ‘Analysis of mercury species in sediments’, Nato Advanced Study Institute, “Metal Speciation in the Environment”. Springer Verlag, in press.
Wilken, R.- D. and Weiler, K.: 1986a, Deutsche Gewässerkundliche Mitteilungen 30, 19.
Wilken, R.- D., Neumann, L. J. R. and Boeddecker, H.: 1986b, ‘Concept, performance and first results from continuously measured heavy metal pollution of a tidal river’, Environmental Contamination, Amsterdam Sept. 1986, CEP Consultants Ltd 1986, Edinburgh.
Wilken, R.-D., Neumann, L.J.R., Christiansen, H., Boeddeker, H.: 1989, International Environment Congress. The Harbour — An Ecological Challenge. Umweltbehörde Hamburg, 158.
Wood, G. M.: 1974, Science 183, 1049.
Zarnegar, P. and Mushak, P.: 1974, Anal. Chem. Acta 69, 389.
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Wilken, RD., Hintelmann, H. Mercury and methylmercury in sediments and suspended particles from the river Elbe, North Germany. Water, Air, and Soil Pollution 56, 427–437 (1991). https://doi.org/10.1007/BF00342289
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DOI: https://doi.org/10.1007/BF00342289