Abstract
We have determined the temperature from SRS spectra of N2-N2, N2-CO2, O2-O2, and CO2-CO2 recorded in wide pressure and temperature ranges. The fitting procedure takes simultaneously into account the Dicke effect and motional narrowing. We have quantified the accuracy of the MEG and ECS-P models for rotational relaxation. The temperature extracted from each model is compared with thermocouple measurements. The influence of vibrational broadening and shifting is discussed in detail.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
D.A. Greenhalgh: Advances in Non-Linear Spectroscopy, ed. by J.H. Clark, R.E. Hester (Wiley, New York 1988) p. 193
D. Robert: Raman Spectroscopy Vibrational Spectra and Structure, ed. by J.R. Durig (Elsevier, New York 1989) p. 17B
G. Millot, B. Lavorel, R. Saint-Loup, H. Berger: J. Phys. (Paris) 46, 1925 (1985)
B. Lavorel, G. Millot, R. Saint-Loup, C. Wenger, H. Berger, J.P. Sala, J. Bonamy, D. Robert: J. Phys. (Paris) 47, 417 (1986)
L.A. Rahn, R.E. Palmer: J. Opt. Soc. Am. B 3, 1164 (1986)
J.P. Sala, J. Bonamy, D. Robert, B. Lavorel, G. Millot, H. Berger: Chem. Phys. 106, 427 (1986)
M.L. Koszykowski, L.A. Rahn, R.E. Palmer, M.E. Coltrin: J. Phys. Chem. 91, 41 (1987)
B. Lavorel, G. Millot, J. Bonamy, D. Robert: Chem. Phys. 115, 69 (1987)
L. Bonamy, J. Bonamy, D. Robert, B. Lavorel, R. Saint-Loup, R. Chaux, J. Santos, H. Berger: J. Chem. Phys. 89, 5568 (1990)
G.O. Sitz, R.L. Farrow: J. Chem. Phys. 93, 7883 (1990)
J.I. Steinfeld, P. Ruttenberg, G. Millot, G. Fanjoux, B. Lavorel: J. Phys. Chem. 95, 9638 (1991)
L. Bonamy, J.M. Thuet, J. Bonamy, D. Robert: J. Chem. Phys. 95, 3361 (1991)
B. Lavorel, B. Oksengorn, D. Fabre, R. Saint-Loup, H. Berger: Mol. Phys. 75, 397 (1992)
M.L. Gonze, R. Saint-Loup, J. Santos, B. Lavorel, R. Chaux, G. Millot, H. Berger, J. Bonamy, L. Bonamy, D. Robert: Chem. Phys. 148, 417 (1990)
J. Bonamy, D. Robert, J.M. Hartmann, M.L. Gonze, R. Saint-Loup, H. Berger: J. Chem. Phys. 91, 5916 (1989)
J. Bonamy, L. Bonamy, D. Robert, M.L. Gonze, G. Millot, B. Lavorel, H. Berger: J. Chem. Phys. 94, 6584 (1991)
G. Millot, R. Saint-Loup, J. Santos, R. Chaux, H. Berger, J. Bonamy: J. Chem. Phys. 96, 961 (1992)
G. Millot, C. Roche, R. Saint-Loup, R. Chaux, H. Berger, J. Santos: Chem. Phys. (in press)
B. Lavorel, G. Millot, R. Saint-Loup, H. Berger, L. Bonamy, J. Bonamy, D. Robert: J. Chem. Phys. 93, 2176 (1990)
B. Lavorel, G. Millot, R. Saint-Loup, H. Berger, L. Bonamy, J. Bonamy, D. Robert: J. Chem. Phys. 93, 2185 (1990)
G.J. Rosasco, L.A. Rahn, W.S. Hurst, R.E. Palmer, S.M. Dohne: J. Chem. Phys. 90, 4059 (1989)
J.P. Looney, G.J. Rosasco, L.A. Rahn, W.S. Hurst, J.W. Hahn: Chem. Phys. Lett. 161, 232 (1989)
R. Chaux, C. Milan, G. Millot, B. Lavorel, R. Saint-Loup, J. Moret-Bailly: J. Opt. (Paris) 19, 3 (1988)
B. Lange, J. Wolfrum: Appl. Phys. B 51, 53 (1990)
S. Kröll, P.E. Bengtsson, M. Alden, D. Nilsson: Appl. Phys. B 51, 25 (1990)
F.M. Porter, D.A. Greenhalgh, P.J. Stopford, D.R. Williams, C.A. Baker: Appl. Phys. B 51, 31 (1991)
M. Woyde, W. Stricker: Appl. Phys. B 50, 519 (1990)
E. Diessel, T. Dreier, B. Lange, J. Wolfrum: Appl. Phys. B 50, 39 (1990)
M.L. Koszykowski, R.L. Farrow, R.E. Palmer: Opt. Lett. 10, 478 (1985)
L. Galatry: Phys. Rev. 122, 1218 (1961)
G. Millot: Dissertation, Dijon (1986)
J.O. Hirshfelder, C.F. Curtis, R.B. Bird: Molecular Theory of Gases and Liquids (Wiley, New York 1954)
J.M. Dymond, E.B. Smith: The Virial Coefficients of Pure Gases and Mixtures, A Critical Compilation (Clarendon, Oxford 1980)
D.E. Gray: American Institute of Physics Handbook, 3rd edn. (McGraw-Hill, New York 1972)
B. Lavorel: Unpublished results
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Millot, G., Lavorel, B., Fanjoux, G. et al. Determination of temperature by stimulated raman scattering of molecular nitrogen, oxygen, and carbon dioxide. Appl. Phys. B 56, 287–293 (1993). https://doi.org/10.1007/BF00325218
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00325218