Summary
CP/DD/MASS 13C-NMR spectra have been obtained for regenerated cellulose samples with different crystallinities as well as for cotton, β-D-glucose, β-D-cellobiose, and cellopentaose. The spectra of the regenerated cellulose samples exhibit broad multiplicities of the C-4 and C-6 resonance lines in a similar manner as those of native cellulose samples such as cotton and ramie, and, in addition, another broad tailing of the C-1 resonance. Since these multiplicities change linearly with crystallinity, it is concluded that they are ascribed to the contributions from the crystalline and noncrystalline components. Effects of hydrogen bonds and conformations of the β-1,4-glycosidic linkage on the chemical shifts are also discussed.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
ATALLA,R.H., GAST,J.C., SINDORF,D.W., BARTUSKA,V.J. and MACIEL,G.E.: J. Am. Chem. Soc. 102, 3249(1980)
AZUMA,J. and KOSHIJIMA,T.: Wood Res. Tech. Notes, Wood Res. Inst., Kyoto Univ. 16, 63(1981), most of references in this review
BULEON,A. and CHANZY,H.: J. Polym. Sci. Polym.Phys. Ed. 16, 833 (1978)
CHU,S.S.C. and JEFFREY,G.A.: Acta Cryst. B24, 830(1968)
EARL,W.L. and VANDERHART,D.L.: J. Am. Chem. Soc. 102, 3251(1980)
EARL,W.L. and VANDERHART,D.L.: Macromolecules 14, 570(1981)
FERRIER,W.G.: Acta Cryst. 13, 678(1960); 16, 1023(1963)
GAST,J.C., ATALLA,R.H. and MCKELVEY,R.D.: Carbohydr. Res. 84, 137(1980)
GOLIN,P.A.J.: Adv. Carbohydr. Chem. and Biochem. 38, 13(1981)
HERMANS,P.H. and WEIDINGER,A.: J. Appl. Phys. 19, 491(1948)
HERMANS,P.H. and WEIDINGER,A.: J. Polym. Sci. 4, 135(1949)
HEYRAUD,A., RINANDO,M., VIGNON,M. and VINCENDON,M.: Biopolymers 18, 167(1979)
HIRAI,A., HORII,F. and KITAMARU,R.: J. Polym. Sci. Polym. Phys. Ed. 18, 1801(1980a)
HIRAI,A., KITAMARU,R., HORII,F. and SAKURADA,I.: Cellulose Chem. Technol. 14, 611(1980b)
HUDSON,C.S. and DALE,J.K.: J. Am. Chem. Soc. 39, 320(1917)
INOUE,Y. and CHUJO,R.: Carbohydr. Res. 60, 367(1978)
IMASHIRO,F., MAEDA,S., TAKEGOSHI,K., TERAO,T. and SAIKA,A., to be published
JACOBSON,R.A., WUNDERLICH,J.A. and LIPSCOMB,W.N.: Acta Cryst. 14, 598(1961)
KITAMARU,R., HORII,F. and MURAYAMA,K.: Polymer Bulletin 7, 583,1982
LEUNG,F., CHANZY,H.D., PEREZ,S. and MARCHESSAULT,R.H.: Can. J. Chem. 54, 1365(1976)
MACIEL,G.E., KOLODZIEJSKI,W.L., BERTRAN,M.S. and DALE,B.E.: Macromolecules 15, 686(1982)
PERLIN,A.S., CYR,N., RITCHIE,R.G.S. and PARFONDRY,A.: Carbohydr. Res. 37, C1(1974)
REES,D.A. and SKERRETT,R.J.: Carbohydr. Res. 7, 334(1968)
SAITO,H. and TABETA,R.: Chem. Lett. 713(1981)
SAITO,H., TABETA,R. and HARADA,T.: Chem. Lett. 571(1981a)
SAITO,H., TABETA,R. and HIRANO,S.: Chem. Lett. 1479(1981b)
SANDARAJAN,P.R. and RAO,V.S.R.: Biopolymers 8, 313(1969)
STEJSKAL,E.O. and SCHAEFER,J.: J. Magn. Reson. 18, 560(1975)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Horii, F., Hirai, A. & Kitamaru, R. Solid-state high-resolution 13C-NMR studies of regenerated cellulose samples with different crystallinities. Polymer Bulletin 8, 163–170 (1982). https://doi.org/10.1007/BF00263023
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00263023