Summary
The reaction of NH4VO3 with S -22 in ammonia in the presence of 2,2′-bipyridine (bipy) and [N(Bu)4]Br gives the mononuclear compound [N(Bu)4][V(O)(S2)2bipy] (1) isolated at room temperature in crystalline form. The X-ray crystal structure determination shows that the vanadium(V) centre is ligated by four sulphur atoms and a nitrogen atom of the bipy ligand forming the equatorial plane of pentagonal bipyramid, an oxygen and the remaining nitrogen atom of the bipy occupying the two apices of the bipyramid.
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References
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Simonnet-Jégat, C., Robert, F. & Sécheresse, F. Synthesis and characterization of the mononuclear oxovanadium-disulphide compound [N(Bu)4][V(O)(S2)2bipy]. Transition Met Chem 19, 379–380 (1994). https://doi.org/10.1007/BF00139118
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DOI: https://doi.org/10.1007/BF00139118