Abstract
A method capable of accurately and selectively measuring Cr3+ in water is required and was therefore studied. The precision and reproducibility of chlorophosphonazo I color reaction spectrophotometry (CCRS) for the selective determination of Cr3+ was improved to be acceptable standards. The CCRS established is therefore an accurate, reproducible and inexpensive method. It also has reasonably good sensitivity and selectivity, and a high sample output. This method should be readily adapted for the routine and selective determination of Cr3+ in bottled mineral drinking water with (or without) the supplementation of Cr3+ or in natural water such as mineral or pipe water with the presence of Cr6+.
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References
A. Pechova and L. Pavlata, Vet. Med., 2007, 52, 1.
J.B. Vincent, Nutr. Rev., 2000, 58, 67.
M.B. Rabinowitz, H.C. Gonick, S.R. Levine, Biol. Trace Elem. Res., 1983, 5, 449.
R.A. Anderson, N.A. Bryden, M.M. Polansky, K. Gautschi, J. Trace Elem. Exp. Med., 1996, 9, 1.
W.T. Cefalu and F.B. Hu, Diabetes Care, 2004, 27, 2741.
WHO, "Trace Elements in Human Nutrition and Health: A Report of a Re-evaluation of the Role of Trace Elements in Human Health and Nutrition", 1996, World Health Organization, Geneva.
UK Food Standards Agency, The Natural Mineral Water, Spring Water and Bottled Drinking Water (England) Regulations 2007 (as amended).
A.H. Smith, Epidemiology, 2008, 19, 24.
WHO, "Guidelines for Drinking-water Quality", 4th ed., 2011, WHO.
A. Zhitkovich, Chem. Res. Toxicol., 2011, 24, 1617.
M. Llobat-Estelles, A.R. Mauri-Aucejo, M.D. Lopez-Catalan, J. Anal. Chem., 2001, 371, 358.
K.G. Kumar and R. Muthuselvi, J. Anal. Chem., 2006, 61, 28.
C.H. Collins, S.H. Pezzin, J.F.L. Rivera, P.S. Bonato, C.C. Windmöller, C. Archundia, K.E. Collins, J. Chromatogr. A, 1997, 789, 469.
S.I. Kim, D.J. Woo, M.H. Lee, G.J. Woo, D.K. Kang, K.W. Cha, Bull. Korean Chem. Soc., 2003, 1517.
J.C.R. Garcia, J.B. Garcia, C.H. Latorre, S.G. Martin, R.M. Crecente, J. Agric. Food Chem., 2005, 53, 6616.
K.L. Mandiwana, N. Panichev, S. Panichev, Food Chem., 2011, 129, 1839.
M. Kwoczek, P. Szefer, E. Hac, M. Grembecka, J. Agric. Food Chem., 2006, 54, 3015.
S. Matsuoka, Y. Nakatsu, K. Takehara, S. Saputro, K. Yoshimura, Anal. Sci., 2006, 22, 1519.
D.T. Gjerde, D.R. Wiederin, F.G. Smith, B.M. Mattson, J. Chromatogr. A, 1993, 640, 73.
M. Tuerkmen and C. Ciminli, Food Chem., 2007, 103, 670.
F. Chang, G.C. Li, M. Haws, T.H. Niu, Food Chem., 2007, 104, 1171.
W. Li, S. Patrick, D. Shrader, T.J. Herrman, S.Y. Dai, Talanta, 2013, 112, 43.
S. Himeno, Y. Nakashima, K. Sano, Anal. Sci., 1998, 14, 369.
Y. Li and H. Xue, Anal. Chim. Acta, 2001, 448, 121.
C.M. Andrle, N. Jakubowski, J.A.C. Broekaert, Spectrochim. Acta, Part B, 1997, 52, 189.
L.V. Tan, T.Q. Hieu, N.V. Cuong, J. Anal. Methods Chem., 2015, Article ID 860649.
A. Mohammadi, M.M. Doroodmand, M.M.R. Sadegh, J. Text. Sci. Eng., 2016, 6, 243.
W. Ahmad, A.S. Bashammakh, A.A. Al-Sibaai, H. Alwael, M.S. El-Shahawi, J. Mol. Liquids, 2016, 224, 1242.
Z.X. Zhao and X.S. Zhang, J. Appl. Spectrosc., 2016, 83, 1084.
X.C. Qiu and Y.Q. Zhu, Microchim. Acta, 1983, 81, 1.
G.J. de Jong and U.A.T. Brinkman, Anal. Chim. Acta, 1978, 98, 243.
H. Staniek, Z. Krejpcio, D. Wieezorek, Biol. Trace Elem. Res., 2016, 171, 192.
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Zhang, H., Wu, W. Estimation of Cr(III) in Water with the Presence of Cr(VI) by Chlorophosphonazo I Color Reaction Spectrophotometry. ANAL. SCI. 34, 305–309 (2018). https://doi.org/10.2116/analsci.34.305
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DOI: https://doi.org/10.2116/analsci.34.305