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Organometallic synthesis of water-soluble ruthenium nanoparticles in the presence of sulfonated diphosphines and cyclodextrins

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Abstract

The organometallic approach was successfully applied to synthesize water-soluble ruthenium nanoparticles displaying interesting catalytic properties in hydrogenation of unsaturated model-substrates. Nanocatalyst synthesis was performed by hydrogenation of the complex [Ru(COD)(COT)] in the presence of sulfonated diphosphines and cyclodextrins as protective agents providing very small ruthenium nanoparticles (ca. 1.2-1.5 nm) with narrow size distribution and high stability. Catalysis results in water evidenced a control of the surface properties of these novel ruthenium nanocatalysts at a supramolecular level.

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Acknowledgments

The authors thank V. Collière and L. Datas (LCC-CNRS and UPS-TEMSCAN) for TEM/HRTEM facilities, P. Lecante (CEMES-CNRS) for WAXS measurements and Y. Coppel and C. Bijani (LCC-CNRS) for NMR studies. This work was supported by CNRS and the Agence Nationale de la Recherche (ANR-09-BLAN-0194) for the financial support of the SUPRANANO program.

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Authors and Affiliations

  1. CNRS, LCC (Laboratoire de Chimie de Coordination), 205 Route de Narbonne, F-31077, Toulouse, France

    Miguel Guerrero & Karine Philippot

  2. UPS, LCC, Université de Toulouse, F-31077, Toulouse, France

    Miguel Guerrero & Karine Philippot

  3. Ecole Nationale Supérieure de Chimie de Rennes, UMR, CNRS 6226, Avenue du General Leclerc, CS 50837, 35 708, RENNES Cedex 7, France

    Nguyet Trang Thanh Chau, Alain Roucoux & Audrey Nowicki-Denicourt

  4. Université Européenne de Bretagne, France

    Nguyet Trang Thanh Chau, Alain Roucoux & Audrey Nowicki-Denicourt

  5. UMR CNRS 8181, Université d’Artois, Rue Jean Souvraz, F-62307, Lens Cedex, France

    Eric Monflier & Hervé Bricout

Authors
  1. Miguel Guerrero
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  2. Nguyet Trang Thanh Chau
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  3. Alain Roucoux
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  4. Audrey Nowicki-Denicourt
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  5. Eric Monflier
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  6. Hervé Bricout
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  7. Karine Philippot
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Correspondence to Karine Philippot.

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Guerrero, M., Chau, N.T.T., Roucoux, A. et al. Organometallic synthesis of water-soluble ruthenium nanoparticles in the presence of sulfonated diphosphines and cyclodextrins. MRS Online Proceedings Library 1675, 219–225 (2014). https://doi.org/10.1557/opl.2014.888

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  • DOI: https://doi.org/10.1557/opl.2014.888

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