Abstract
A multi-analytical approach was used to investigate Roman lead-glazed ceramic artefacts from archaeological excavations at Pompeii and Herculaneum (Italy) aiming at defining the production technology of both glaze and ceramic body, by way of integrated investigations. The chemical, structural, and micro-morphological characterisations were performed using a combination of laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), optical microscopy (OM), scanning electron microscopy (SEM), and micro-Raman spectroscopy. Fragments of artefacts (skyphoi, oil lamps, bowls, askoi, amphorae, krateres) of great historical and archaeological interest were sampled. LA-ICP-MS was used to determine the elemental composition by virtue of its effective lateral resolution, its ability to detect most elements and also to analyse comparably small samples. All the archaeological objects were coated with a lead-based glaze produced using a lead oxide-plus-quartz mixture, with sodium/potassium feldspars added as a flux and two different metals used: copper and iron. Two types of ceramic pastes have been identified, but chemometric techniques support the hypothesis of a Campanian provenance for the raw materials. Degradation phenomena such as the partial devitrification of the glaze, i.e. the slow structural reorganisation towards stable crystalline phases, and the leaching by mineral dissolution in the soil, were determined.
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Arthur, P. (1979). An Italian flagon from Roman Colchester. The Antiquaries Journal, 59, 392–397. DOI: 10.1017/s0003581500079786.
Burgio, L., & Clark, R. J. H. (2001). Library of FT-Raman spectra of pigments, minerals, pigment media and vernishes, and supplement to existing library of Raman spectra of pigments with visible excitation. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 57, 1491–1521. DOI: 10.1016/s1386-1425(00)00495-9.
Cochrane, E. E., & Neff, H. (2006). Investigating compositional diversity among Fijian ceramics with laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS): implications for interaction studies on geologically similar islands. Journal of Archaeological Science, 33, 378–390. DOI: 10.1016/j.jas.2005.08.003.
Colomban, P., Sagon, G., & Faurel, X. (2001). Differentiation of antique ceramics from the Raman spectra of their coloured glazes and paintings. Journal of Raman Spectroscopy, 32, 351–360. DOI: 10.1002/jrs.704.
Colomban, P., Milande, V., & Le Bihan, L. (2004). On-site Raman analysis of Iznik pottery glazes and pigments. Journal of Raman Spectroscopy, 35, 527–535. DOI: 10.1002/jrs.1163.
Colomban, P., Tournie, A., & Bellot-Gurlet, L. (2006). Raman identification of glassy silicates used in ceramics, glass and jewellery: a tentative differentiation guide. Journal of Raman Spectroscopy, 37, 841–852. DOI: 10.1002/jrs.1515.
De Benedetto, G. E., Acquafredda, P., Masieri, M., Quarta, G., Sabbatini, L., Zambonin, P. G., Tite, M., & Walton, M. (2004). Investigation on Roman lead glaze from Canosa: Results of chemical analyses. Archaeometry, 46, 615–624. DOI: 10.1111/j.1475-4754.2004.00177.x.
Desbat, A. (1986). Céramiques romaines à glaçure plombifère des fouilles de Lyon (Hauts-de-Saint-Just, Rue des Farges, La Solitude). Figlina, 7, 105–124. (in French)
Desbat A. (1995). Les productions précoces de céramiques à glaçure plombifère delavalléedu Rhône. Rei Cretariae Romanae Fautores Acta, 34, 39–47. (in French)
Di Gioia, E. (2006). La ceramica invetriata in area vesuviana. Studi della Soprintendenza Archeologica di Pompei. Roma, Italy: ĽErma di Bretschneider. (in Italian)
Génin, D., Desbat, A., Elaigne, S., Laroche, C., & Dangréaux, B. (1996). Les productions de l’atelier de la Muette. Gallia, 53, 41–191. (in French)
Giannossa, L. C., De Benedetto, G. E., Laviano, R., Pallara, M., & Mangone, A. (2012). Archaeometry in the Vesuvian area: Technological teatures of thin-walled ware. In D. Braekmans, J. Honings, & P. Degryse (Eds.), Proceedings of 39th International Symposium on Archaeometry: 50 years of ISA, May 28–June 1, 2012 (pp. 157–163). Leuven, Belgium: KU Leuven.
Giannossa, L. C., Acquaviva, M., De Benedetto, G. E., Acquafredda, P., Laviano, R., & Mangone, A. (2014). Methodology of a combined approach: analytical techniques to identify technology and raw materials used in thin-walled pottery from Herculaneum and Pompeii. Analytical Methods, 6, 3490–3499. DOI: 10.1039/c3ay42195c.
Greene, K. (2007). Late Hellenistic and early Roman invention and innovation: The case of lead-glazed pottery. American Journal of Archaeology, 111, 653–671. DOI: 10.3764/aja.111.4.653.
Halicz, L., & Günther, D. (2004). Quantitative analysis of silicates using LA-ICP-MS with liquid calibration. Journal of Analytical Atomic Spectrometry, 19, 1539–1545. DOI: 10.1039/b410132d.
Hatcher, H., Kaczmarczyk, A., Scherer, A., & Symonds, R. P. (1994). Chemical classification and provenance of some Roman glazed ceramics. American Journal of Archaeology, 98, 431–456. DOI: 10.2307/506438.
Heimann, R. B., & Maggetti, M. (1981). Experiments on simulated burial of calcareous Terra Sigillata (mineralogical change). Preliminary results. In M. J. Hughes (Ed.), Scientific studies in ancient ceramics (British Museum Occasional Paper 19, pp. 163–177). London, UK: British Museum.
Hochuli-Gysel, A. (2002). La céramique à glaçure plombifère d’Asie Mineure et du bassin méditerranéen oriental (du 1er s. av. J.-C. au 1er s. ap. J.-C.). In F. Blondé, P. Ballet, & J. F. Salles (Eds.), Céramiques hellénistiques et romaines: Productions et diffusion en Méditerranée orientale (Chypre, Égypte et côte syro-palestinienne) (Actes du colloque à la Maison de l’Orient méditerranéen Jean Pouilloux, pp. 303–319). Lyon, France: Maison de l’Orient Méditerranéen. (in French)
Hurst, D., & Freestone, I. (1996). Lead glazing technique from a medieval kiln site at Hanley Swan, Worcestershire. Medieval Ceramics, 20, 13–18.
James, W. D., Dahlin, E. S., & Carlson, D. L. (2005). Chemical compositional studies of archaeological artifacts: Comparison of LA-ICP-MS to INAA measurements. Journal of Radioanalytical and Nuclear Chemistry, 263, 697–702. DOI: 10.1007/s10967-005-0645-5.
Liu, Y. S., Hu, Z. C., Gao, S., Günther, D., Xu, J. A., Gao, C. G., & Chen, H. H. (2008). In situ analysis of major and trace elements of anhydrous minerals by LA-ICP-MS without applying an internal standard. Chemical Geology, 257, 34–43. DOI: 10.1016/j.chemgeo.2008.08.004.
Maccabruni, C. (1987). Ceramica romana con invetriatura al piombo. In P. Lévęque, & J. P. Morel (Eds.), Cèramiques hellenistique et romaines (Annales scientifiques de l’Université de Besançcon, pp. 167–182). Besancon, France: Université de Besançcon. (in Italian)
Maccabruni, C. (1994). Ceramica invetriata con decorazione a rilievo. Nuovi ritrovamenti dal territorio pavese. Rei Cretariae Romanae Fautores Acta, 34, 49–61. (in Italian)
Mangone, A., Giannossa, L. C., Laviano, R., Fioriello, C. S., & Traini, A. (2009). Investigations by various analytical techniques to the correct classification of archaeological finds and delineation of technological features: Late Roman lamps from Egnatia: From imports to local production. Microchemical Journal, 91, 214–221. DOI: 10.1016/j.microc.2008.11.006.
Mangone, A., De Benedetto, G. E., Fico, D., Giannossa, L. C., Laviano, R., Sabbatini, L., van der Werf, I. D., & Traini, A. (2011a). A multianalytical study of archaeological faience from Vesuvian area as a valid tool to investigate provenance and technological features. New Journal of Chemistry, 35, 2860–2868. DOI: 10.1039/c1nj20626e.
Mangone, A., Giannossa, L. C., De Benedetto, G. E., Laviano, R., Traini, A., & Sabbatini, L. (2011b). Ceramica a pareti sottili da Ercolano: un’indagine archeometrica. In A. Coralini (Ed.), Vesuviana. Bologna, Italy: Antequem. (in Italian)
Martin, A. (1992). La ceramica invetriata romana: la testimonianza dell’Area NE delle Terme del Nuotatore ad Ostia. In L. Paroli (Ed.), Proceedings of the Seminar at Certosa di Pontigliano, February 23–24, 1990 (pp. 323–329). Firenze, Italy. (in Italian)
Molera, J., Pradell, T., Salvadó, N., & Vendrell-Saz, M. (2001). Interaction between clay bodies and lead glazes. Journal of the American Ceramic Society, 84, 1120–1128. DOI: 10.1111/j.1151-2916.2001.tb00799.x.
Pérez-Arantegui, J., Uruñuela, M. I., & Castillo, J. R. (1996). Roman glazed ceramics in the Western Mediterranean: Chemical characterization by inductively coupled plasma atomic emission spectrometry of ceramic bodies. Journal of Archaeological Science, 23, 903–914. DOI: 10.1006/jasc.1996.0085.
Picon, M., & Vichy, M. (1974). Recherches sur la composition des céramiques de Lyon. Revue Archéologique de l’Est et du Centre-Est Consacrée aux Antiquités Nationales, 25(1), 37–59. (in French).
Picon, M., & Desbat, A. (1986). Note sur l’origine des céramiques à glaçure plombifère, généralement bicolore, des IIème et IIIème siècles, de Vienne et Saint-Romain-en-Gal, Figlina, 7, 125–127. (in French)
Resano, M., Pérez-Arantegui, J., Garcia-Ruiz, E., & Vanhaecke, F. (2005). Laser ablation-inductively coupled plasma mass spectrometry for the fast and direct characterization of antique glazed ceramics. Journal of Analytical Atomic Spectrometry, 20, 508–514. DOI: 10.1039/b500691k.
Šelih, V. S., & van Elteren, J. T. (2011). Quantitative multielement mapping of ancient glass using a simple and robust LA-ICP-MS rastering procedure in combination with image analysis. Analytical & Bioanalytical Chemistry, 401, 745–755. DOI: 10.1007/s00216-011-5119-8.
Soricelli, G. 1988. Osservazioni intorno ad un cratere in ceramica invetriata da Pompei. Rivista di Studi Pompeiani, 1988(II), 248–254. (in Italian)
Stoner, W. D., & Glascock, M. D. (2012). The forest or the trees? Behavioral and methodological considerations for geochemical characterization of heavily-tempered ceramic pastes using NAA and LA-ICP-MS. Journal of Archaeological Science, 39, 2668–2683. DOI: 10.1016/j.jas.2012.04.011.
van Elteren, J. T., Tennent, N. H., & Šelih, V. S. (2009). Multielement quantification of ancient/historic glasses by laser ablation inductively coupled plasma mass spectrometry using sum normalization calibration. Analytica Chimica Acta, 644, 1–9. DOI: 10.1016/j.aca.2009.04.025.
Walton, M. S., & Tite, M. S. (2010). Production technology of Roman lead-glazed pottery and its continuance into late antiquity. Archaeometry, 52, 733–759. DOI: 10.1111/j.1475-4754.2009.00506.x.
Ziviello, V. (1989). Le terrecotte invetriate. In L. De Luca (Ed.), Le collezioni del Museo Nazionale di Napoli (pp. 204). Roma, Italy: Archivio fotografico Pedicini. (in Italian)
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Giannossa, L.C., Fico, D., Pennetta, A. et al. Integrated investigations for the characterisation of Roman lead-glazed pottery from Pompeii and Herculaneum (Italy). Chem. Pap. 69, 1033–1043 (2015). https://doi.org/10.1515/chempap-2015-0110
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DOI: https://doi.org/10.1515/chempap-2015-0110