Abstract
The electrochemical behavior of a titanium–aluminum hybrid electrode in aqueous solutions of electrolytes containing halide ions (F– and Cl–) was studied. The effects of current density, solution composition, and ratio of the working surface area of titanium and aluminum on the anodic dissolution rate of a Ti‒Al hybrid electrode and its electrochemical characteristics were revealed. The joint anodic dissolution of aluminum and titanium in the aqueous media under study made it possible to obtain precursors of the highly disperse oxide system Al2O3–TiO2. Data of X-ray and electron-microscopic analysis confirmed the results obtained.
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References
Gusev, A.I., Nanomaterialy, nanostruktury, nanotekhnologii (Nanomaterials, Nanostructures, Nanotechnologies), Moscow: FIZMATLIT, 2007.
Mor, G.K., Shankar, K., Paulose, M., et al., Nano Lett., 2006, vol. 6, no. 2, p.215.
Chauhan, R., Kushwaha, R., and Bahadur, L., Mater. Chem. Phys., 2013, vol. 139, nos. 2–3, p.525.
Xiong, Y., Tang, Z., Wang, Y., et al., J. Adv. Ceram., 2015, vol. 4, no. 2, p.152.
Zhu, J., Liu, X., Wang, X., et al., Sens. Actuators, B, 2015, vol. 221, no. 1, p.450.
Liu, L., Chen, H., and Yang, F., Sep. Purif. Technol., 2014, vol. 133, p.22.
Huang, M., Chen, Y., Huang, C.-H., et al., Chem. Eng. J., 2015, vol. 279, p.904.
Yang, W.-E., Hsu, M.-L., Lin, M.-C., et al., J. Alloys Compd., 2009, vol. 479, nos. 1–2, p.642.
Pan, X., Yang, M.Q., Fu, X., et al., Nanoscale, 2013, vol. 5, p. 3601.
Zunic, V., Skapin, S.D., and Suvorov, D., J. Am. Ceram. Soc., 2015, vol. 98, no. 10, p. 2997.
Wu, J.M., J. Cryst. Growth, 2004, vol. 269, nos. 2–4, p.347.
Gong, D., Grimes, C.A., and Varghese, O.K., Mater. Res. Soc., 2001, vol. 16, no. 12, p. 3331
Liu, G., Wang, K., Hoivik, N., and Jakobsen, H., Sol. Energy Mater. Sol. Cells, 2012, vol. 98, pp. 24–38.
Kelkar, G.P. and Carim, A.H., J. Am. Ceram. Soc., 1995, vol. 78, no. 3, p.572.
Das, K., Choudhury, P., and Das, S., J. Phase Equilib. Diffus., 2002, vol. 23, no. 6, p.525.
Gu, Z., Luo, L., and Chen, S., Indian J. Chem. Technol., 2009, vol. 16, no. 2, p.175.
Abd El All, S. and El-Shobaky, G.A., J. Alloys Compd., 2009, vol. 479, nos. 1–2, p.91.
Starowicz, M. and Stypula, B., Eur. J. Inorg. Chem., 2008, vol. 2008, no. 6, p.869.
Starowicz, M., Starowicz, P., and Stypula, B., J. Solid State Electrochem., 2014, vol. 18, p. 3065.
Tomashov, N.D. and Chernova, G.P., Teoriya korrozii i korrozionno-stoikie konstruktsionnye splavy (Theory of Corrosion and Corrosion-Resistant Structure Alloys), Moscow: Metallurgiya, 1986.
Yakimenko, L.M., Elektrodnye materialy v prikladnoi elektrokhimii (Electrode Materials in Applied Electrochemistry), Moscow: Khimiya, 1977.
Tomashov, N.D. and Al’tovskii, R.M., Korroziya i zashchita titana (Corrosion and Protection of Titanium), Moscow: Mashgiz, 1963.
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Original Russian Text © A.F. Dresvyannikov, I.O. Grigoryeva, L.R. Khairullina, 2017, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2017, Vol. 53, No. 6, pp. 623–631.
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Dresvyannikov, A.F., Grigoryeva, I.O. & Khairullina, L.R. Anodic Behavior of a Titanium–Aluminum Hybrid Electrode: Formation of Hydroxide-Oxide Compounds. Prot Met Phys Chem Surf 53, 1050–1058 (2017). https://doi.org/10.1134/S2070205117060090
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DOI: https://doi.org/10.1134/S2070205117060090