Abstract
The results from 15 years of studies performed at the Samara State Technical University in the field of developing highly active sulfide catalysts for the hydrotreatment of straight-run and refractory low-grade oil fractions with the use of molybdenum and tungsten heteropoly compounds (HPCs) as precursors are presented. A wide range of HPCs with Anderson and Keggin structures is studied in the synthesis of sulfide catalysts. The order of activities in the hydrodesulfurization of sulfur compounds and the hydrogenation of unsaturated hydrocarbons are established for the heteroelements incorporated into HPCs. Catalytic activity—HPC heteroatom electronegativity correlations are revealed. Special attention is given to controlling the selectivity of catalysts with respect to parallel hydrogenation and hydrodesulfurization reactions. A wide variety of highly active sulfide catalysts for the hydrotreatment of diesel fuel, catalytic cracking gasoline, vacuum gas oil, and lube feedstocks is developed. The techniques for their synthesis and activation (sulfidation) are substantiated. The developments are patented and are close to being introduced at oil refineries whenever they are ready.
Article PDF
We’re sorry, something doesn't seem to be working properly.
Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.
Avoid common mistakes on your manuscript.
References
Technical Regulation on the Requirements to Automobile and Aviation Gasoline, Diesel and Ship Fuel, Jet Engine Fuel, and Furnace Oil. Russian Federation Government decree no. 118, February 27, 2008.
Nacamura, D. and Silvy, R.P., Oil Gas J., 2002, vol. 100, pp. 48–56.
Duplyakin, V.K., Ross. Khim. Zh., 2008, vol. 51, no. 4, pp. 11–22.
On the Road Map “Application of Nanotechnologies in Catalytic Oil Refining Processes.” Explanatory note to the RUSNANO’s Board Meeting, July 27, 2010.
Stanislaus, A., Marafi, A., and Rana, M.S., Catal. Today, 2010, vol. 153, nos. 1–2, pp. 1–68.
Parlevliet, F. and Eijsbouts, S., Catal. Today., 2008, vol. 130, no. 1, pp. 254–264.
Mitusova, T.N. and Kalinina, M.V., Neftepererab. Neftekhim., 2004, no. 10, pp. 11–14.
Kashin, O.N., Ermolenko, A.D., Firsova, T.G., and Rudin, M.G., Neftepererab. Neftekhim., 2005, no. 5, pp. 32–38.
Krylov, I.F., Emel’yanov, V.E., Nikitina, E.A., Nizhegorodskii, B.N., and Rudyak, K.B., Chem. Technol. Fuels Oils, 2005, vol. 41, no. 6, pp. 423–428.
Smirnov, V.K., Gantsev, V.A., and Polunkin, Ya.M., Neftepererab. Neftekhim., 2004, no. 4, pp. 38–42.
Yelshin, A.I., Aliev, R.R., Tomin, V.P., and Krashchuk, S.G., Chem. Technol. Fuels Oils, 2005, vol. 41, no. 3, pp. 184–187.
Podratz, D.J., Kleemeir, K., Turner, W.J., and Moyse, B.M., Oil Gas J., 1999, vol. 97, no. 20, pp. 41–43.
Kolotov, V.Yu., Novichikhin, D.N., Silinskaya, Ya.N., and Beda, T.V., Neftepererab. Neftekhim., 2005, no. 12, pp. 6–10.
Oltyrev, A.G., Fedorov, A.A., Kudakov, S.A., Golubev, A.B., Levin, O.V., Selezneva, V.N., and Shiryagina, L.A., Neftepererab. Neftekhim., 2001, no. 7, pp. 6–11.
Smirnov, V.K., Irisova, K.N., Talisman, E.L., Akhmatdinov, Sh.T., and Shaikhetdinov, R.N., Neftepererab. Neftekhim., 2005, no. 12, pp. 10–15.
Chernysheva, E.A., Usova, T.V., and Izmashkina, A.I., Chem. Technol. Fuels Oils, 2005, vol. 41, no. 2, pp. 146–150.
Tomina, N.N., Pimerzin, A.A., and Moiseev, I.K., Ross. Khim. Zh., 2008, vol. 52, no. 4, pp. 41–52.
Handbook of Petroleum Processing, Jones, D.S.J and Pujadó, P.R., Eds., Dordrecht: Springer, 2006.
Catalyst Preparation: Science and Engineering, Regalbuto, J., Ed., Boca Raton, FL: Taylor & Francis/CRC Press, 2007.
Startsev, A.N., Sul’fidnye katalizatory gidroochistki: sintez, struktura, svoistva (Sulfide Catalysts of Hydrotreatment: Synthesis, Structure, Properties), Novosibirsk: Geo, 2007.
Afanasiev, P., Catal. Today, http://www.sciencedirect.com/science/article/pii/S0920586114002776. Cited February 22, 2015.
Spojakina, A.A., Kostova, N.G., Yuchnovski, I.N., Shopov, D.M., Yurieva, T.M., and Shokhireva, T.Kh., Appl. Catal., 1988, vol. 39, pp. 333–342.
Tomina, N.N., Loginova, A.N., and Sharikhina, M.A., Neftekhimiya, 1989, vol. 29, no. 1, pp. 25–29.
Spojakina, A., Damyanova, S., Shopov, D., Shokhireva, T.Kh., and Yurieva, T.M., React. Kinet. Catal. Lett., 1985, vol. 27, no. 2, pp. 333–336.
Tomina, N.N., Eremina, Yu.V., Pimerzin, A.A., Zhilkina, E.O., Sharikhina, M.A., and Loginova, A.N., Neftekhimiya, 2004, vol. 44, no. 4, pp. 274–277.
Spojakina, A.A., Kraleva, E.U., Jirátová, K., Kociánová, J., and Petrov, L., Bulg. Chem. Commun., 2002, vol. 34, nos. 3–4, pp. 495–504.
Maitra, A.M., Cant, N.W., and Trimm, D.L., Appl. Catal., vol. 48, no. 1, pp. 187–197.
Spojakina, A.A., Gigov, B., and Shopov, D.M., React. Kinet. Catal. Lett., 1982, vol. 19, nos. 1–2, pp. 11–14.
Cabello, C.I., Muñoz, M., Payen, E., and Thomas, H.J., Catal. Lett., 2004, vol. 92, nos. 1–2, pp. 69–73.
Shokhireva, T.Kh., Yurieva, T.M., Altinnikov, A.A., Anufrienko, V.F., Plyasova, L.M., and Litvak, G.S., React. Kinet. Catal. Lett., 1992, vol. 47, no. 2, pp. 177–185.
Spozhakina, A.A., Kostova, N.G., and Tsolovski, I.A., Kinet. Katal., 1982, vol. 23, no. 2, pp. 456–461.
Griboval, A., Blanchard, P., Gengembre, L., Fournier, M., Dubois, J.L., and Bernard, J.R., J. Catal., 1999, vol. 188, no. 1, pp. 102–110.
Cabello, C.I., Muñoz, M., Botto, I.L., and Payen, E., Thermochim. Acta, 2006, vol. 447, no. 1, pp. 22–29.
Lamonier, C., Martin, C., Mazurelle, J., Harle, V., Guillaume, D., and Payen, E., Appl. Catal., B, 2007, vol. 70, nos. 1–4, pp. 548–556.
Blanchard, P., Lamonier, C., and Griboval, A., Appl. Catal., A, 2007, vol. 322, pp. 33–45.
Cabello, C.I., Botto, I.L., and Thomas, H.J., Appl. Catal., A, 2000, vol. 197, no. 1, pp. 79–86.
Pettiti, I., Botto, I.L., Cabello, C.I., Colonna, S., Faticanti, M., Minelli, G., Porta, P., and Thomas, J.H., Appl. Catal., A, 2001, vol. 220, nos. 1–2, pp. 113–121.
Nikulshin, P.A., Tomina, N.N., Pimerzin, A.A., Stakheev, A.Yu., Mashkovsky, I.S., and Kogan, V.M., Appl. Catal., A, 2011, vol. 393, nos. 1–2, pp. 146–152.
Maksimov, N.M., Tomina, N.N., and Pimerzin, A.A., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2010, vol. 53, no. 11, pp. 73–76.
Chianelli, R.R., Daage, M., and Ledoux, M.J., Adv. Catal., 1994, vol. 40, pp. 177–232.
Nikulshin, P.A., Mozhaev, A.V., Maslakov, K.I., Pimerzin, A.A., and Kogan, V.M., Appl. Catal., B, 2014, vols. 158–159, pp. 161–174.
Mozhaev, A.V., Nikul’shin, P.A., Pimerzin, Al.A., and Konovalov, V.V., Pet. Chem., 2012, vol. 52, no. 1, pp. 41–48.
Nikulshin, P.A., Mozhaev, A.V., Pimerzin, Al.A., Konovalov, V.V., and Pimerzin, A.A., Fuel, 2012, vol. 100, pp. 24–33.
Nikul’shin, P.A., Mozhaev, A.V., Pimerzin, A.A., Tomina, N.N., Konovalov, V.V., and Kogan, V.M., Kinet. Catal., 2011, vol. 52, no. 6, pp. 862–875.
Nikul’shin, P.A., Mozhaev, A.V., Ishutenko, D.I., Minaev, P.P., Lyashenko, A.I., and Pimerzin, A.A., Kinet. Catal., 2012, vol. 53, no. 5, pp. 620–631.
Nikulshin, P.A., Ishutenko, D.I., Mozhaev, A.A., Maslakov, K.I., and Pimerzin, A.A., J. Catal., 2014, vol. 312, pp. 152–169.
Nikul’shin, P.A., Tomina, N.N., Ishutenko, D.I., and Pimerzin, A.A., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2008, vol. 51, no. 9, pp. 51–55.
Dorokhov, V.S., Ishutenko, D.I., Nikul’shin, P.A., Kotsareva, K.V., Trusova, E.A., Bondarenko, T.N., Eliseev, O.L., Lapidus, A.L., Rozhdestvenskaya, N.N., and Kogan, V.M., Kinet. Catal., 2013, vol. 54, no. 2, pp. 243–252.
Dorokhov, V.S., Ishutenko, D.I., Nikul’shin, P.A., Eliseev, O.L., Rozhdestvenskaya, N.N., Kogan, V.M., and Lapidus, A.L., Dokl. Chem., 2013, vol. 451, no. 3, pp. 191–195.
Handbook of Petroleum Refining Processes, Meyers, R.A., Ed., New York: McGraw-Hill, 2003.
RF Patent 2486010, Byull. Izobret., 2013, no. 18.
Lynch, T.R., Process Chemistry of Lubricant Base Stocks, Boca Raton, FL: Taylor & Francis/CRC Press, 2008.
Tsvetkov, O.N. and Shkol’nikov, V.M., Katal. Neftepererab. Prom-sti, 2008, no. 3, pp. 12–16.
RF Patent 2497585, Byull. Izobret., 2013, no. 23.
Antonov, S.A., Tomina, N.N., Safronova, T.N., and Maksimov, N.M., Bashk. Khim. Zh., 2011, vol. 18, no. 3, pp. 11–17.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.A. Pimerzin, N.N. Tomina, P.A. Nikul’shin, N.M. Maksimov, A.V. Mozhaev, D.I. Ishutenko, E.E. Vishnevskaya, 2014, published in Kataliz v Promyshlennosti.
Rights and permissions
About this article
Cite this article
Pimerzin, A.A., Tomina, N.N., Nikul’shin, P.A. et al. Catalysts based on molybdenum and tungsten heteropoly compounds for the hydrotreatment of oil fractions. Catal. Ind. 7, 30–37 (2015). https://doi.org/10.1134/S2070050415010110
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2070050415010110
Keywords
- sulfide catalysts
- molybdenum heteropoly compounds
- tungsten heteropoly compounds
- activity
- selectivity
- catalyst sulfidation
- hydrodesulfurization of sulfur compounds
- hydrogenation of unsaturated hydrocarbons
- hydrotreatment
- catalytic cracking gasoline
- diesel fraction
- vacuum gas oil
- lube fractions
- technical regulations
- Euro-5